4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate

In the title hydrated salt, C(16)H(13)ClN(3) (+)·Cl(−)·2H(2)O, a small twist is evident in the cation so that the chloro­benzene ring is not coplanar with the central hydrazinyl group [the N—C—C—C torsion angle = −4.8 (12)°]. The conformation about the imine N=C bond [1.284 (10) Å] is E. The compone...

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Autores principales: Tiekink, Edward R. T., Wardell, Solange M. S. V., Wardell, James L., Ferreira, Marcelle de Lima, de Souza, Marcus V. N., Kaiser, Carlos R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379418/
https://www.ncbi.nlm.nih.gov/pubmed/22719616
http://dx.doi.org/10.1107/S1600536812022660
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author Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
Ferreira, Marcelle de Lima
de Souza, Marcus V. N.
Kaiser, Carlos R.
author_facet Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
Ferreira, Marcelle de Lima
de Souza, Marcus V. N.
Kaiser, Carlos R.
author_sort Tiekink, Edward R. T.
collection PubMed
description In the title hydrated salt, C(16)H(13)ClN(3) (+)·Cl(−)·2H(2)O, a small twist is evident in the cation so that the chloro­benzene ring is not coplanar with the central hydrazinyl group [the N—C—C—C torsion angle = −4.8 (12)°]. The conformation about the imine N=C bond [1.284 (10) Å] is E. The components of the structure are connected into a three-dimensional architecture via O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds. One water H atom is disposed over two sites of equal occupancy.
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spelling pubmed-33794182012-06-20 4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate Tiekink, Edward R. T. Wardell, Solange M. S. V. Wardell, James L. Ferreira, Marcelle de Lima de Souza, Marcus V. N. Kaiser, Carlos R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title hydrated salt, C(16)H(13)ClN(3) (+)·Cl(−)·2H(2)O, a small twist is evident in the cation so that the chloro­benzene ring is not coplanar with the central hydrazinyl group [the N—C—C—C torsion angle = −4.8 (12)°]. The conformation about the imine N=C bond [1.284 (10) Å] is E. The components of the structure are connected into a three-dimensional architecture via O—H⋯O, O—H⋯Cl and N—H⋯Cl hydrogen bonds. One water H atom is disposed over two sites of equal occupancy. International Union of Crystallography 2012-05-23 /pmc/articles/PMC3379418/ /pubmed/22719616 http://dx.doi.org/10.1107/S1600536812022660 Text en © Tiekink et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiekink, Edward R. T.
Wardell, Solange M. S. V.
Wardell, James L.
Ferreira, Marcelle de Lima
de Souza, Marcus V. N.
Kaiser, Carlos R.
4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate
title 4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate
title_full 4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate
title_fullStr 4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate
title_full_unstemmed 4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate
title_short 4-[(E)-2-(2-Chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate
title_sort 4-[(e)-2-(2-chloro­benzyl­idene)hydrazin-1-yl]quinolin-1-ium chloride dihydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379418/
https://www.ncbi.nlm.nih.gov/pubmed/22719616
http://dx.doi.org/10.1107/S1600536812022660
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