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(1S,5R,7R,30S)-14-Deoxyisogarcinol
The title compound, C(38)H(50)O(5) {systematic name: 10-(3-hydroxybenzoyl)-2,2,7,7-tetramethyl-3,6,8-tris(3-methylbut-2-enyl)-3,4,4a,5,6,7-hexahydro-4a,8-methano-2H-cycloocta[b]pyran-9,11(8H)-dione}, is a polyisoprenylated benzophenone, isolated for the first time from the fruits of Garcin...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379428/ https://www.ncbi.nlm.nih.gov/pubmed/22719626 http://dx.doi.org/10.1107/S1600536812020788 |
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author | Kaur, Ranjeet Vasudev, Prema G. Chattopadhyay, Sunil K. |
author_facet | Kaur, Ranjeet Vasudev, Prema G. Chattopadhyay, Sunil K. |
author_sort | Kaur, Ranjeet |
collection | PubMed |
description | The title compound, C(38)H(50)O(5) {systematic name: 10-(3-hydroxybenzoyl)-2,2,7,7-tetramethyl-3,6,8-tris(3-methylbut-2-enyl)-3,4,4a,5,6,7-hexahydro-4a,8-methano-2H-cycloocta[b]pyran-9,11(8H)-dione}, is a polyisoprenylated benzophenone, isolated for the first time from the fruits of Garcinia indica during our investigation of bioactive compounds from this plant and their large-scale extraction. The relative configuration of the title compound was chosen based on comparison of its spectroscopic and optical rotation data with that of the isomorphous and isostructural compound isogarcinol, whose absolute configuration is known. The crystal packing features O—H⋯O hydrogen bonds. A Cambridge Structural Database analysis revealed that the crystal structure reported here is isomorphous and isostructural with that of isogarcinol. |
format | Online Article Text |
id | pubmed-3379428 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33794282012-06-20 (1S,5R,7R,30S)-14-Deoxyisogarcinol Kaur, Ranjeet Vasudev, Prema G. Chattopadhyay, Sunil K. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(38)H(50)O(5) {systematic name: 10-(3-hydroxybenzoyl)-2,2,7,7-tetramethyl-3,6,8-tris(3-methylbut-2-enyl)-3,4,4a,5,6,7-hexahydro-4a,8-methano-2H-cycloocta[b]pyran-9,11(8H)-dione}, is a polyisoprenylated benzophenone, isolated for the first time from the fruits of Garcinia indica during our investigation of bioactive compounds from this plant and their large-scale extraction. The relative configuration of the title compound was chosen based on comparison of its spectroscopic and optical rotation data with that of the isomorphous and isostructural compound isogarcinol, whose absolute configuration is known. The crystal packing features O—H⋯O hydrogen bonds. A Cambridge Structural Database analysis revealed that the crystal structure reported here is isomorphous and isostructural with that of isogarcinol. International Union of Crystallography 2012-05-23 /pmc/articles/PMC3379428/ /pubmed/22719626 http://dx.doi.org/10.1107/S1600536812020788 Text en © Kaur et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Kaur, Ranjeet Vasudev, Prema G. Chattopadhyay, Sunil K. (1S,5R,7R,30S)-14-Deoxyisogarcinol |
title | (1S,5R,7R,30S)-14-Deoxyisogarcinol |
title_full | (1S,5R,7R,30S)-14-Deoxyisogarcinol |
title_fullStr | (1S,5R,7R,30S)-14-Deoxyisogarcinol |
title_full_unstemmed | (1S,5R,7R,30S)-14-Deoxyisogarcinol |
title_short | (1S,5R,7R,30S)-14-Deoxyisogarcinol |
title_sort | (1s,5r,7r,30s)-14-deoxyisogarcinol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379428/ https://www.ncbi.nlm.nih.gov/pubmed/22719626 http://dx.doi.org/10.1107/S1600536812020788 |
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