(2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide

The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio­amide form. The two rings in the mol­ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol­ecules are linked...

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Detalles Bibliográficos
Autores principales: Jacob, Jinsa Mary, Sithambaresan, M., Kurup, M. R. Prathapachandra
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379435/
https://www.ncbi.nlm.nih.gov/pubmed/22719633
http://dx.doi.org/10.1107/S1600536812022520
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author Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_facet Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
author_sort Jacob, Jinsa Mary
collection PubMed
description The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio­amide form. The two rings in the mol­ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol­ecules are linked through pairs of N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra­molecular N—H⋯N, O—H⋯O and C—H⋯π inter­actions are also present.
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spelling pubmed-33794352012-06-20 (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide Jacob, Jinsa Mary Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(14)BrN(3)O(2)S, adopts an E,E conformation with respect to the azomethine and hydrazinic bonds and exists in the thio­amide form. The two rings in the mol­ecule are twisted away from each other, making a dihedral angle of 69.13 (13)°. In the crystal, mol­ecules are linked through pairs of N—H⋯O and O—H⋯S hydrogen bonds, leading to the formation of inversion dimers which are stacked along the a axis. Intra­molecular N—H⋯N, O—H⋯O and C—H⋯π inter­actions are also present. International Union of Crystallography 2012-05-23 /pmc/articles/PMC3379435/ /pubmed/22719633 http://dx.doi.org/10.1107/S1600536812022520 Text en © Jacob et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Jacob, Jinsa Mary
Sithambaresan, M.
Kurup, M. R. Prathapachandra
(2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide
title (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide
title_full (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide
title_fullStr (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide
title_full_unstemmed (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide
title_short (2E)-2-(5-Bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-N-phenyl­hydrazine­carbo­thio­amide
title_sort (2e)-2-(5-bromo-2-hy­droxy-3-meth­oxy­benzyl­idene)-n-phenyl­hydrazine­carbo­thio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379435/
https://www.ncbi.nlm.nih.gov/pubmed/22719633
http://dx.doi.org/10.1107/S1600536812022520
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AT kurupmrprathapachandra 2e25bromo2hydroxy3methoxybenzylidenenphenylhydrazinecarbothioamide

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