2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole

In the title compound, C(18)H(14)N(4)O, the mol­ecules are disordered about a crystallographic twofold axis, leading to 50:50 disorder of the O- and N-atom sites within the oxazole ring. As a consequence, symmetry-related oxazole C—N and C—O bonds are averaged. The oxazole ring makes a dihedral angl...

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Autores principales: Campos-Gaxiola, José J., Höpfl, Herbert, Aguirre, Gerardo, Parra-Hake, Miguel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379436/
https://www.ncbi.nlm.nih.gov/pubmed/22719634
http://dx.doi.org/10.1107/S1600536812022611
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author Campos-Gaxiola, José J.
Höpfl, Herbert
Aguirre, Gerardo
Parra-Hake, Miguel
author_facet Campos-Gaxiola, José J.
Höpfl, Herbert
Aguirre, Gerardo
Parra-Hake, Miguel
author_sort Campos-Gaxiola, José J.
collection PubMed
description In the title compound, C(18)H(14)N(4)O, the mol­ecules are disordered about a crystallographic twofold axis, leading to 50:50 disorder of the O- and N-atom sites within the oxazole ring. As a consequence, symmetry-related oxazole C—N and C—O bonds are averaged. The oxazole ring makes a dihedral angle of 6.920 (1)° with the pyridyl ring in the 2-position and 60.960 (2)° with the pyridyl rings in the 4- and 5-positions.
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spelling pubmed-33794362012-06-20 2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole Campos-Gaxiola, José J. Höpfl, Herbert Aguirre, Gerardo Parra-Hake, Miguel Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(14)N(4)O, the mol­ecules are disordered about a crystallographic twofold axis, leading to 50:50 disorder of the O- and N-atom sites within the oxazole ring. As a consequence, symmetry-related oxazole C—N and C—O bonds are averaged. The oxazole ring makes a dihedral angle of 6.920 (1)° with the pyridyl ring in the 2-position and 60.960 (2)° with the pyridyl rings in the 4- and 5-positions. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379436/ /pubmed/22719634 http://dx.doi.org/10.1107/S1600536812022611 Text en © Campos-Gaxiola et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Campos-Gaxiola, José J.
Höpfl, Herbert
Aguirre, Gerardo
Parra-Hake, Miguel
2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole
title 2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole
title_full 2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole
title_fullStr 2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole
title_full_unstemmed 2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole
title_short 2,4,5-Tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole
title_sort 2,4,5-tris(pyridin-4-yl)-4,5-dihydro-1,3-oxazole
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379436/
https://www.ncbi.nlm.nih.gov/pubmed/22719634
http://dx.doi.org/10.1107/S1600536812022611
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