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Tris[2-(2H-indazol-2-yl)eth­yl]amine

The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant...

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Detalles Bibliográficos
Autores principales: Ovalle, Saúl, Elizondo Martínez, Perla, Pérez Rodríguez, Nancy, Bernès, Sylvain, Flores-Alamo, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379441/
https://www.ncbi.nlm.nih.gov/pubmed/22719639
http://dx.doi.org/10.1107/S1600536812022027
Descripción
Sumario:The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant 2H-indazole heterocycles surrounding the symmetry axis, affording a claw-like shaped mol­ecule. Two symmetry-related indazole planes in the mol­ecule make an acute angle of 60.39 (4)°. The lone pair of the tertiary N atom is located inside the cavity, and should thus be inactive (as a ligand). In the crystal, neither significant π–π nor C—H⋯π inter­actions between molecules are found.