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Tris[2-(2H-indazol-2-yl)ethyl]amine
The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379441/ https://www.ncbi.nlm.nih.gov/pubmed/22719639 http://dx.doi.org/10.1107/S1600536812022027 |
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author | Ovalle, Saúl Elizondo Martínez, Perla Pérez Rodríguez, Nancy Bernès, Sylvain Flores-Alamo, Marcos |
author_facet | Ovalle, Saúl Elizondo Martínez, Perla Pérez Rodríguez, Nancy Bernès, Sylvain Flores-Alamo, Marcos |
author_sort | Ovalle, Saúl |
collection | PubMed |
description | The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant 2H-indazole heterocycles surrounding the symmetry axis, affording a claw-like shaped molecule. Two symmetry-related indazole planes in the molecule make an acute angle of 60.39 (4)°. The lone pair of the tertiary N atom is located inside the cavity, and should thus be inactive (as a ligand). In the crystal, neither significant π–π nor C—H⋯π interactions between molecules are found. |
format | Online Article Text |
id | pubmed-3379441 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33794412012-06-20 Tris[2-(2H-indazol-2-yl)ethyl]amine Ovalle, Saúl Elizondo Martínez, Perla Pérez Rodríguez, Nancy Bernès, Sylvain Flores-Alamo, Marcos Acta Crystallogr Sect E Struct Rep Online Organic Papers The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant 2H-indazole heterocycles surrounding the symmetry axis, affording a claw-like shaped molecule. Two symmetry-related indazole planes in the molecule make an acute angle of 60.39 (4)°. The lone pair of the tertiary N atom is located inside the cavity, and should thus be inactive (as a ligand). In the crystal, neither significant π–π nor C—H⋯π interactions between molecules are found. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379441/ /pubmed/22719639 http://dx.doi.org/10.1107/S1600536812022027 Text en © Ovalle et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ovalle, Saúl Elizondo Martínez, Perla Pérez Rodríguez, Nancy Bernès, Sylvain Flores-Alamo, Marcos Tris[2-(2H-indazol-2-yl)ethyl]amine |
title | Tris[2-(2H-indazol-2-yl)ethyl]amine |
title_full | Tris[2-(2H-indazol-2-yl)ethyl]amine |
title_fullStr | Tris[2-(2H-indazol-2-yl)ethyl]amine |
title_full_unstemmed | Tris[2-(2H-indazol-2-yl)ethyl]amine |
title_short | Tris[2-(2H-indazol-2-yl)ethyl]amine |
title_sort | tris[2-(2h-indazol-2-yl)ethyl]amine |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379441/ https://www.ncbi.nlm.nih.gov/pubmed/22719639 http://dx.doi.org/10.1107/S1600536812022027 |
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