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Tris[2-(2H-indazol-2-yl)eth­yl]amine

The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant...

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Autores principales: Ovalle, Saúl, Elizondo Martínez, Perla, Pérez Rodríguez, Nancy, Bernès, Sylvain, Flores-Alamo, Marcos
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379441/
https://www.ncbi.nlm.nih.gov/pubmed/22719639
http://dx.doi.org/10.1107/S1600536812022027
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author Ovalle, Saúl
Elizondo Martínez, Perla
Pérez Rodríguez, Nancy
Bernès, Sylvain
Flores-Alamo, Marcos
author_facet Ovalle, Saúl
Elizondo Martínez, Perla
Pérez Rodríguez, Nancy
Bernès, Sylvain
Flores-Alamo, Marcos
author_sort Ovalle, Saúl
collection PubMed
description The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant 2H-indazole heterocycles surrounding the symmetry axis, affording a claw-like shaped mol­ecule. Two symmetry-related indazole planes in the mol­ecule make an acute angle of 60.39 (4)°. The lone pair of the tertiary N atom is located inside the cavity, and should thus be inactive (as a ligand). In the crystal, neither significant π–π nor C—H⋯π inter­actions between molecules are found.
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spelling pubmed-33794412012-06-20 Tris[2-(2H-indazol-2-yl)eth­yl]amine Ovalle, Saúl Elizondo Martínez, Perla Pérez Rodríguez, Nancy Bernès, Sylvain Flores-Alamo, Marcos Acta Crystallogr Sect E Struct Rep Online Organic Papers The title tertiary amine, C(27)H(27)N(7), a potential tripodal ligand for coordination chemistry, crystallizes with the central N atom located on a threefold axis of a trigonal cell. The gauche conformation of the N(amime)—CH(2)—CH(2)—N(indazole) chain [torsion angle = −64.2 (2)°] places the pendant 2H-indazole heterocycles surrounding the symmetry axis, affording a claw-like shaped mol­ecule. Two symmetry-related indazole planes in the mol­ecule make an acute angle of 60.39 (4)°. The lone pair of the tertiary N atom is located inside the cavity, and should thus be inactive (as a ligand). In the crystal, neither significant π–π nor C—H⋯π inter­actions between molecules are found. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379441/ /pubmed/22719639 http://dx.doi.org/10.1107/S1600536812022027 Text en © Ovalle et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ovalle, Saúl
Elizondo Martínez, Perla
Pérez Rodríguez, Nancy
Bernès, Sylvain
Flores-Alamo, Marcos
Tris[2-(2H-indazol-2-yl)eth­yl]amine
title Tris[2-(2H-indazol-2-yl)eth­yl]amine
title_full Tris[2-(2H-indazol-2-yl)eth­yl]amine
title_fullStr Tris[2-(2H-indazol-2-yl)eth­yl]amine
title_full_unstemmed Tris[2-(2H-indazol-2-yl)eth­yl]amine
title_short Tris[2-(2H-indazol-2-yl)eth­yl]amine
title_sort tris[2-(2h-indazol-2-yl)eth­yl]amine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379441/
https://www.ncbi.nlm.nih.gov/pubmed/22719639
http://dx.doi.org/10.1107/S1600536812022027
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