2-Chloro-7,8,9,10-tetra­hydro­cyclo­hepta­[b]indol-6(5H)-one

In the title mol­ecule, C(13)H(12)ClNO, the dihedral angle between the benzene and pyrrole rings is 1.38 (9)°. The cyclo­heptene ring adopts a distorted twist chair and sofa conformation. Inter­molecular N—H⋯O hydrogen bonds form an R (2) (2)(10) loop in the crystal packing. Further, weak C—H⋯O and...

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Detalles Bibliográficos
Autores principales: Archana, R., Yamuna, E., Rajendra Prasad, K. J., Thiruvalluvar, A., Butcher, R. J., Gupta, Sushil K., Öztürk Yildirim, Sema
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379447/
https://www.ncbi.nlm.nih.gov/pubmed/22719645
http://dx.doi.org/10.1107/S1600536812022945
Descripción
Sumario:In the title mol­ecule, C(13)H(12)ClNO, the dihedral angle between the benzene and pyrrole rings is 1.38 (9)°. The cyclo­heptene ring adopts a distorted twist chair and sofa conformation. Inter­molecular N—H⋯O hydrogen bonds form an R (2) (2)(10) loop in the crystal packing. Further, weak C—H⋯O and C—H⋯π (involving the benzene ring) inter­actions are found in the crystal structure.

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