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N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide

In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chloro­benzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the mol­ecule approximates to a U shape. Both the C—S—N—C confo...

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Detalles Bibliográficos
Autores principales: Khan, Islam Ullah, Ejaz, Farid, Sidra, Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379469/
https://www.ncbi.nlm.nih.gov/pubmed/22719667
http://dx.doi.org/10.1107/S1600536812023434
Descripción
Sumario:In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chloro­benzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the mol­ecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intra­molecular C—H⋯O inter­action generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(20) loops. A second N—H⋯O hydrogen bond links the dimers into (101) layers.