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N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide

In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chloro­benzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the mol­ecule approximates to a U shape. Both the C—S—N—C confo...

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Detalles Bibliográficos
Autores principales: Khan, Islam Ullah, Ejaz, Farid, Sidra, Harrison, William T. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379469/
https://www.ncbi.nlm.nih.gov/pubmed/22719667
http://dx.doi.org/10.1107/S1600536812023434
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author Khan, Islam Ullah
Ejaz,
Farid, Sidra
Harrison, William T. A.
author_facet Khan, Islam Ullah
Ejaz,
Farid, Sidra
Harrison, William T. A.
author_sort Khan, Islam Ullah
collection PubMed
description In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chloro­benzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the mol­ecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intra­molecular C—H⋯O inter­action generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(20) loops. A second N—H⋯O hydrogen bond links the dimers into (101) layers.
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spelling pubmed-33794692012-06-20 N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide Khan, Islam Ullah Ejaz, Farid, Sidra Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chloro­benzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the mol­ecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intra­molecular C—H⋯O inter­action generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(20) loops. A second N—H⋯O hydrogen bond links the dimers into (101) layers. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379469/ /pubmed/22719667 http://dx.doi.org/10.1107/S1600536812023434 Text en © Khan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khan, Islam Ullah
Ejaz,
Farid, Sidra
Harrison, William T. A.
N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide
title N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide
title_full N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide
title_fullStr N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide
title_full_unstemmed N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide
title_short N-[4-(4-Chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide
title_sort n-[4-(4-chloro­benzene­sulfonamido)­phenyl­sulfon­yl]acetamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379469/
https://www.ncbi.nlm.nih.gov/pubmed/22719667
http://dx.doi.org/10.1107/S1600536812023434
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