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N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide
In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U shape. Both the C—S—N—C confo...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379469/ https://www.ncbi.nlm.nih.gov/pubmed/22719667 http://dx.doi.org/10.1107/S1600536812023434 |
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author | Khan, Islam Ullah Ejaz, Farid, Sidra Harrison, William T. A. |
author_facet | Khan, Islam Ullah Ejaz, Farid, Sidra Harrison, William T. A. |
author_sort | Khan, Islam Ullah |
collection | PubMed |
description | In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intramolecular C—H⋯O interaction generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(20) loops. A second N—H⋯O hydrogen bond links the dimers into (101) layers. |
format | Online Article Text |
id | pubmed-3379469 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33794692012-06-20 N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide Khan, Islam Ullah Ejaz, Farid, Sidra Harrison, William T. A. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(13)ClN(2)O(5)S(2), the dihedral angles between the central benzene ring and the pendant chlorobenzene ring and the N-acetyl group are 82.35 (5) and 79.71 (6)°, respectively, and the overall conformation of the molecule approximates to a U shape. Both the C—S—N—C conformations are gauche, but with opposite senses [torsion angles = −59.29 (15) and 63.68 (16)°]. An intramolecular C—H⋯O interaction generates an S(6) ring. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds generate R (2) (2)(20) loops. A second N—H⋯O hydrogen bond links the dimers into (101) layers. International Union of Crystallography 2012-05-26 /pmc/articles/PMC3379469/ /pubmed/22719667 http://dx.doi.org/10.1107/S1600536812023434 Text en © Khan et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Khan, Islam Ullah Ejaz, Farid, Sidra Harrison, William T. A. N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
title |
N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
title_full |
N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
title_fullStr |
N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
title_full_unstemmed |
N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
title_short |
N-[4-(4-Chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
title_sort | n-[4-(4-chlorobenzenesulfonamido)phenylsulfonyl]acetamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379469/ https://www.ncbi.nlm.nih.gov/pubmed/22719667 http://dx.doi.org/10.1107/S1600536812023434 |
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