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2-(2-Hy­droxy-3-meth­oxy­phen­yl)-1H-benzimidazol-3-ium perchlorate

In the title mol­ecular salt, C(14)H(13)N(2)O(2) (+)·ClO(4) (−), the ring systems in the cation are almost coplanar [dihedral angle = 5.53 (13)°]. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds generate S(6) and S(5) rings, respectively. In the crystal, the two H atoms involved in the intra­molecula...

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Detalles Bibliográficos
Autores principales: Chen, Chuan, Li, Hong-Xing, Hou, Guang-Feng, Li, Guang-Ming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379475/
https://www.ncbi.nlm.nih.gov/pubmed/22719673
http://dx.doi.org/10.1107/S1600536812023422
Descripción
Sumario:In the title mol­ecular salt, C(14)H(13)N(2)O(2) (+)·ClO(4) (−), the ring systems in the cation are almost coplanar [dihedral angle = 5.53 (13)°]. Intra­molecular N—H⋯O and O—H⋯O hydrogen bonds generate S(6) and S(5) rings, respectively. In the crystal, the two H atoms involved in the intra­molecular hydrogen bonds also participate in inter­molecular links to acceptor O atoms of the perchlorate anions. A simple inter­molecular N—H⋯O bond also occurs. Together, these form a double-chain structure along [101].