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N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide
In the title molecule, C(17)H(16)N(2)O(4)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.546 (4) and 0.281 (4) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The molecular structure is stabilized b...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379476/ https://www.ncbi.nlm.nih.gov/pubmed/22719674 http://dx.doi.org/10.1107/S1600536812022805 |
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author | Aman, Farhana Siddiqui, Waseeq Ahmad Ashraf, Adnan Siddiqui, Hamid Latif Parvez, Masood |
author_facet | Aman, Farhana Siddiqui, Waseeq Ahmad Ashraf, Adnan Siddiqui, Hamid Latif Parvez, Masood |
author_sort | Aman, Farhana |
collection | PubMed |
description | In the title molecule, C(17)H(16)N(2)O(4)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.546 (4) and 0.281 (4) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The molecular structure is stabilized by an intramolecular O—H⋯O hydrogen bond. The two aromatic rings are inclined to one another by 42.32 (11)°. In the crystal, molecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers. The dimers are linked via a series of C—H⋯O interactions, leading to the formation of a three-dimensional network. |
format | Online Article Text |
id | pubmed-3379476 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33794762012-06-20 N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide Aman, Farhana Siddiqui, Waseeq Ahmad Ashraf, Adnan Siddiqui, Hamid Latif Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title molecule, C(17)H(16)N(2)O(4)S, the heterocyclic thiazine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.546 (4) and 0.281 (4) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The molecular structure is stabilized by an intramolecular O—H⋯O hydrogen bond. The two aromatic rings are inclined to one another by 42.32 (11)°. In the crystal, molecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers. The dimers are linked via a series of C—H⋯O interactions, leading to the formation of a three-dimensional network. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379476/ /pubmed/22719674 http://dx.doi.org/10.1107/S1600536812022805 Text en © Aman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Aman, Farhana Siddiqui, Waseeq Ahmad Ashraf, Adnan Siddiqui, Hamid Latif Parvez, Masood N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide |
title |
N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide |
title_full |
N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide |
title_fullStr |
N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide |
title_full_unstemmed |
N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide |
title_short |
N-Benzyl-4-hydroxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothiazine-3-carboxamide |
title_sort | n-benzyl-4-hydroxy-2-methyl-1,1-dioxo-2h-1λ(6),2-benzothiazine-3-carboxamide |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379476/ https://www.ncbi.nlm.nih.gov/pubmed/22719674 http://dx.doi.org/10.1107/S1600536812022805 |
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