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N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide

In the title mol­ecule, C(17)H(16)N(2)O(4)S, the heterocyclic thia­zine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.546 (4) and 0.281 (4) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The mol­ecular structure is stabilized b...

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Autores principales: Aman, Farhana, Siddiqui, Waseeq Ahmad, Ashraf, Adnan, Siddiqui, Hamid Latif, Parvez, Masood
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379476/
https://www.ncbi.nlm.nih.gov/pubmed/22719674
http://dx.doi.org/10.1107/S1600536812022805
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author Aman, Farhana
Siddiqui, Waseeq Ahmad
Ashraf, Adnan
Siddiqui, Hamid Latif
Parvez, Masood
author_facet Aman, Farhana
Siddiqui, Waseeq Ahmad
Ashraf, Adnan
Siddiqui, Hamid Latif
Parvez, Masood
author_sort Aman, Farhana
collection PubMed
description In the title mol­ecule, C(17)H(16)N(2)O(4)S, the heterocyclic thia­zine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.546 (4) and 0.281 (4) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The mol­ecular structure is stabilized by an intra­molecular O—H⋯O hydrogen bond. The two aromatic rings are inclined to one another by 42.32 (11)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers. The dimers are linked via a series of C—H⋯O inter­actions, leading to the formation of a three-dimensional network.
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spelling pubmed-33794762012-06-20 N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide Aman, Farhana Siddiqui, Waseeq Ahmad Ashraf, Adnan Siddiqui, Hamid Latif Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(17)H(16)N(2)O(4)S, the heterocyclic thia­zine ring adopts a half-chair conformation, with the S and N atoms displaced by 0.546 (4) and 0.281 (4) Å, respectively, on opposite sides of the mean plane formed by the remaining ring atoms. The mol­ecular structure is stabilized by an intra­molecular O—H⋯O hydrogen bond. The two aromatic rings are inclined to one another by 42.32 (11)°. In the crystal, mol­ecules are linked by pairs of N—H⋯O hydrogen bonds, forming inversion dimers. The dimers are linked via a series of C—H⋯O inter­actions, leading to the formation of a three-dimensional network. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379476/ /pubmed/22719674 http://dx.doi.org/10.1107/S1600536812022805 Text en © Aman et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Aman, Farhana
Siddiqui, Waseeq Ahmad
Ashraf, Adnan
Siddiqui, Hamid Latif
Parvez, Masood
N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide
title N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide
title_full N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide
title_fullStr N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide
title_full_unstemmed N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide
title_short N-Benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2H-1λ(6),2-benzothia­zine-3-carboxamide
title_sort n-benzyl-4-hy­droxy-2-methyl-1,1-dioxo-2h-1λ(6),2-benzothia­zine-3-carboxamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379476/
https://www.ncbi.nlm.nih.gov/pubmed/22719674
http://dx.doi.org/10.1107/S1600536812022805
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