Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate

In the cation of the title salt, C(24)H(24)N(7) (3+)·3C(6)H(2)N(3)O(7) (−)·2C(2)H(3)N, the three benzimidazolium ring systems are oriented to each other at dihedral angles of 10.42 (7), 23.98 (7) and 22.17 (7)°. In the crystal, the cation links to the adjacent picrate anions via N—H⋯O hydrogen bonds...

Descripción completa

Detalles Bibliográficos
Autores principales: Bai, Ying, Yuan, Jing-Kun, Wang, Hua, Pan, Guo-Long, Wu, Hui-Lu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379477/
https://www.ncbi.nlm.nih.gov/pubmed/22719675
http://dx.doi.org/10.1107/S160053681202329X
_version_ 1782236209251090432
author Bai, Ying
Yuan, Jing-Kun
Wang, Hua
Pan, Guo-Long
Wu, Hui-Lu
author_facet Bai, Ying
Yuan, Jing-Kun
Wang, Hua
Pan, Guo-Long
Wu, Hui-Lu
author_sort Bai, Ying
collection PubMed
description In the cation of the title salt, C(24)H(24)N(7) (3+)·3C(6)H(2)N(3)O(7) (−)·2C(2)H(3)N, the three benzimidazolium ring systems are oriented to each other at dihedral angles of 10.42 (7), 23.98 (7) and 22.17 (7)°. In the crystal, the cation links to the adjacent picrate anions via N—H⋯O hydrogen bonds; one of independent acetonitrile solvent mol­ecules is also linked to the cation via an N—H⋯N hydrogen bond.
format Online
Article
Text
id pubmed-3379477
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33794772012-06-20 Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate Bai, Ying Yuan, Jing-Kun Wang, Hua Pan, Guo-Long Wu, Hui-Lu Acta Crystallogr Sect E Struct Rep Online Organic Papers In the cation of the title salt, C(24)H(24)N(7) (3+)·3C(6)H(2)N(3)O(7) (−)·2C(2)H(3)N, the three benzimidazolium ring systems are oriented to each other at dihedral angles of 10.42 (7), 23.98 (7) and 22.17 (7)°. In the crystal, the cation links to the adjacent picrate anions via N—H⋯O hydrogen bonds; one of independent acetonitrile solvent mol­ecules is also linked to the cation via an N—H⋯N hydrogen bond. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379477/ /pubmed/22719675 http://dx.doi.org/10.1107/S160053681202329X Text en © Bai et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Bai, Ying
Yuan, Jing-Kun
Wang, Hua
Pan, Guo-Long
Wu, Hui-Lu
Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate
title Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate
title_full Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate
title_fullStr Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate
title_full_unstemmed Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate
title_short Tris(1H-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate
title_sort tris(1h-benzimidazol-3-ium-2-ylmeth­yl)amine tris­(2,4,6-trinitro­phenolate) acetonitrile disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379477/
https://www.ncbi.nlm.nih.gov/pubmed/22719675
http://dx.doi.org/10.1107/S160053681202329X
work_keys_str_mv AT baiying tris1hbenzimidazol3ium2ylmethylaminetris246trinitrophenolateacetonitriledisolvate
AT yuanjingkun tris1hbenzimidazol3ium2ylmethylaminetris246trinitrophenolateacetonitriledisolvate
AT wanghua tris1hbenzimidazol3ium2ylmethylaminetris246trinitrophenolateacetonitriledisolvate
AT panguolong tris1hbenzimidazol3ium2ylmethylaminetris246trinitrophenolateacetonitriledisolvate
AT wuhuilu tris1hbenzimidazol3ium2ylmethylaminetris246trinitrophenolateacetonitriledisolvate

Ejemplares similares