Cargando…
7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one
The title compound, C(15)H(17)O(6)P, was obtained from a reaction of 4-methyl-7-hydroxycoumarin and 2-chloro-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide. There are two molecules in the asymmetric unit in which the benzopyran ring system is almost planar [r.m.s. deviation for each molecule = 0.003...
Autores principales: | , , |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379479/ https://www.ncbi.nlm.nih.gov/pubmed/22719677 http://dx.doi.org/10.1107/S1600536812023513 |
_version_ | 1782236209712463872 |
---|---|
author | Zhao, Yan-Ru Hou, Xu-Feng Xu, Zhi-Hong |
author_facet | Zhao, Yan-Ru Hou, Xu-Feng Xu, Zhi-Hong |
author_sort | Zhao, Yan-Ru |
collection | PubMed |
description | The title compound, C(15)H(17)O(6)P, was obtained from a reaction of 4-methyl-7-hydroxycoumarin and 2-chloro-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide. There are two molecules in the asymmetric unit in which the benzopyran ring system is almost planar [r.m.s. deviation for each molecule = 0.003 Å]. In the crystal, C—H⋯O hydrogen bonds and π–π stacking interactions [with centroid–centroid distances of 3.743 (3) and 3.727 (3) Å] link the two molecules. The dioxaphosphorinane ring adopts a chair conformation in both asymmetric molecules. |
format | Online Article Text |
id | pubmed-3379479 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33794792012-06-20 7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one Zhao, Yan-Ru Hou, Xu-Feng Xu, Zhi-Hong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(15)H(17)O(6)P, was obtained from a reaction of 4-methyl-7-hydroxycoumarin and 2-chloro-5,5-dimethyl-1,3,2-dioxaphosphinane 2-oxide. There are two molecules in the asymmetric unit in which the benzopyran ring system is almost planar [r.m.s. deviation for each molecule = 0.003 Å]. In the crystal, C—H⋯O hydrogen bonds and π–π stacking interactions [with centroid–centroid distances of 3.743 (3) and 3.727 (3) Å] link the two molecules. The dioxaphosphorinane ring adopts a chair conformation in both asymmetric molecules. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379479/ /pubmed/22719677 http://dx.doi.org/10.1107/S1600536812023513 Text en © Zhao et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Zhao, Yan-Ru Hou, Xu-Feng Xu, Zhi-Hong 7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one |
title | 7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one |
title_full | 7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one |
title_fullStr | 7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one |
title_full_unstemmed | 7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one |
title_short | 7-[(5,5-Dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2H-chromen-2-one |
title_sort | 7-[(5,5-dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)oxy]-4-methyl-2h-chromen-2-one |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379479/ https://www.ncbi.nlm.nih.gov/pubmed/22719677 http://dx.doi.org/10.1107/S1600536812023513 |
work_keys_str_mv | AT zhaoyanru 755dimethyl2oxido132dioxaphosphinan2yloxy4methyl2hchromen2one AT houxufeng 755dimethyl2oxido132dioxaphosphinan2yloxy4methyl2hchromen2one AT xuzhihong 755dimethyl2oxido132dioxaphosphinan2yloxy4methyl2hchromen2one |