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1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione
In the title compound, C(18)H(19)N(3)O(2)S, the thiazine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379482/ https://www.ncbi.nlm.nih.gov/pubmed/22719680 http://dx.doi.org/10.1107/S1600536812022982 |
Sumario: | In the title compound, C(18)H(19)N(3)O(2)S, the thiazine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the two double bonds in the R (2)C=N—N=C(CH(3))Ar grouping are Z and E, respectively. In the crystal, inversion dimers linked by pairs of C—H⋯O interactions generate R (2) (2)(8) and R (2) (2)(12) loops, as parts of infinite chains along the a-axis direction. |
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