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1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione

In the title compound, C(18)H(19)N(3)O(2)S, the thia­zine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the...

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Autores principales: Shafiq, Muhammad, Khan, Islam Ullah, Arshad, Muhammad Nadeem, Bukhari, Iftikhar Hussain, Ejaz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379482/
https://www.ncbi.nlm.nih.gov/pubmed/22719680
http://dx.doi.org/10.1107/S1600536812022982
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author Shafiq, Muhammad
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Bukhari, Iftikhar Hussain
Ejaz,
author_facet Shafiq, Muhammad
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Bukhari, Iftikhar Hussain
Ejaz,
author_sort Shafiq, Muhammad
collection PubMed
description In the title compound, C(18)H(19)N(3)O(2)S, the thia­zine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the two double bonds in the R (2)C=N—N=C(CH(3))Ar grouping are Z and E, respectively. In the crystal, inversion dimers linked by pairs of C—H⋯O inter­actions generate R (2) (2)(8) and R (2) (2)(12) loops, as parts of infinite chains along the a-axis direction.
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spelling pubmed-33794822012-06-20 1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione Shafiq, Muhammad Khan, Islam Ullah Arshad, Muhammad Nadeem Bukhari, Iftikhar Hussain Ejaz, Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(19)N(3)O(2)S, the thia­zine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the two double bonds in the R (2)C=N—N=C(CH(3))Ar grouping are Z and E, respectively. In the crystal, inversion dimers linked by pairs of C—H⋯O inter­actions generate R (2) (2)(8) and R (2) (2)(12) loops, as parts of infinite chains along the a-axis direction. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379482/ /pubmed/22719680 http://dx.doi.org/10.1107/S1600536812022982 Text en © Shafiq et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Shafiq, Muhammad
Khan, Islam Ullah
Arshad, Muhammad Nadeem
Bukhari, Iftikhar Hussain
Ejaz,
1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title 1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_full 1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_fullStr 1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_full_unstemmed 1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_short 1-Ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1H-2λ(6),1-benzothia­zine-2,2-dione
title_sort 1-ethyl-4-[1-(1-phenyl­ethyl­idene)hydrazin-2-yl­idene]-3,4-dihydro-1h-2λ(6),1-benzothia­zine-2,2-dione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379482/
https://www.ncbi.nlm.nih.gov/pubmed/22719680
http://dx.doi.org/10.1107/S1600536812022982
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