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1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione
In the title compound, C(18)H(19)N(3)O(2)S, the thiazine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379482/ https://www.ncbi.nlm.nih.gov/pubmed/22719680 http://dx.doi.org/10.1107/S1600536812022982 |
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author | Shafiq, Muhammad Khan, Islam Ullah Arshad, Muhammad Nadeem Bukhari, Iftikhar Hussain Ejaz, |
author_facet | Shafiq, Muhammad Khan, Islam Ullah Arshad, Muhammad Nadeem Bukhari, Iftikhar Hussain Ejaz, |
author_sort | Shafiq, Muhammad |
collection | PubMed |
description | In the title compound, C(18)H(19)N(3)O(2)S, the thiazine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the two double bonds in the R (2)C=N—N=C(CH(3))Ar grouping are Z and E, respectively. In the crystal, inversion dimers linked by pairs of C—H⋯O interactions generate R (2) (2)(8) and R (2) (2)(12) loops, as parts of infinite chains along the a-axis direction. |
format | Online Article Text |
id | pubmed-3379482 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33794822012-06-20 1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione Shafiq, Muhammad Khan, Islam Ullah Arshad, Muhammad Nadeem Bukhari, Iftikhar Hussain Ejaz, Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(19)N(3)O(2)S, the thiazine ring adopts an envelope conformation, with the S atom displaced by 0.732 (1) Å from the other atoms of the ring. The phenyl ring is oriented at a dihedral angle of 79.33 (7)° with respect to the fused benzene ring. The conformations about the two double bonds in the R (2)C=N—N=C(CH(3))Ar grouping are Z and E, respectively. In the crystal, inversion dimers linked by pairs of C—H⋯O interactions generate R (2) (2)(8) and R (2) (2)(12) loops, as parts of infinite chains along the a-axis direction. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379482/ /pubmed/22719680 http://dx.doi.org/10.1107/S1600536812022982 Text en © Shafiq et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Shafiq, Muhammad Khan, Islam Ullah Arshad, Muhammad Nadeem Bukhari, Iftikhar Hussain Ejaz, 1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione |
title | 1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione |
title_full | 1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione |
title_fullStr | 1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione |
title_full_unstemmed | 1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione |
title_short | 1-Ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1H-2λ(6),1-benzothiazine-2,2-dione |
title_sort | 1-ethyl-4-[1-(1-phenylethylidene)hydrazin-2-ylidene]-3,4-dihydro-1h-2λ(6),1-benzothiazine-2,2-dione |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379482/ https://www.ncbi.nlm.nih.gov/pubmed/22719680 http://dx.doi.org/10.1107/S1600536812022982 |
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