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1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene
In the title compound, C(10)H(9)Cl(2)NO(3), the dihedral angle between the benzene ring and the plane of the nitro group is 39.1 (1)°, while that between the benzene ring and the plane through the three C and two Cl atoms of the dichloroallyloxy unit is 40.1 (1)°. In the crystal, C—H⋯O hydrogen bo...
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Formato: | Online Artículo Texto |
Lenguaje: | English |
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International Union of Crystallography
2012
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379484/ https://www.ncbi.nlm.nih.gov/pubmed/22719682 http://dx.doi.org/10.1107/S1600536812023057 |
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author | Ren, Dong-mei |
author_facet | Ren, Dong-mei |
author_sort | Ren, Dong-mei |
collection | PubMed |
description | In the title compound, C(10)H(9)Cl(2)NO(3), the dihedral angle between the benzene ring and the plane of the nitro group is 39.1 (1)°, while that between the benzene ring and the plane through the three C and two Cl atoms of the dichloroallyloxy unit is 40.1 (1)°. In the crystal, C—H⋯O hydrogen bonds to the nitro groups form chains along the b axis. These chains are linked by inversion-related pairs of Cl⋯O interactions at a distance of 3.060 (3) Å, forming sheets approximately parallel to [-201] and generating R (2) (2)(18) rings. π–π contacts between benzene rings in adjacent sheets, with centroid–centroid distances of 3.671 (2) Å, stack molecules along c. |
format | Online Article Text |
id | pubmed-3379484 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33794842012-06-20 1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene Ren, Dong-mei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(9)Cl(2)NO(3), the dihedral angle between the benzene ring and the plane of the nitro group is 39.1 (1)°, while that between the benzene ring and the plane through the three C and two Cl atoms of the dichloroallyloxy unit is 40.1 (1)°. In the crystal, C—H⋯O hydrogen bonds to the nitro groups form chains along the b axis. These chains are linked by inversion-related pairs of Cl⋯O interactions at a distance of 3.060 (3) Å, forming sheets approximately parallel to [-201] and generating R (2) (2)(18) rings. π–π contacts between benzene rings in adjacent sheets, with centroid–centroid distances of 3.671 (2) Å, stack molecules along c. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379484/ /pubmed/22719682 http://dx.doi.org/10.1107/S1600536812023057 Text en © Dong-mei Ren 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ren, Dong-mei 1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene |
title | 1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene |
title_full | 1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene |
title_fullStr | 1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene |
title_full_unstemmed | 1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene |
title_short | 1-(3,3-Dichloroallyloxy)-4-methyl-2-nitrobenzene |
title_sort | 1-(3,3-dichloroallyloxy)-4-methyl-2-nitrobenzene |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379484/ https://www.ncbi.nlm.nih.gov/pubmed/22719682 http://dx.doi.org/10.1107/S1600536812023057 |
work_keys_str_mv | AT rendongmei 133dichloroallyloxy4methyl2nitrobenzene |