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1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene

In the title compound, C(10)H(9)Cl(2)NO(3), the dihedral angle between the benzene ring and the plane of the nitro group is 39.1 (1)°, while that between the benzene ring and the plane through the three C and two Cl atoms of the dichloro­all­yloxy unit is 40.1 (1)°. In the crystal, C—H⋯O hydrogen bo...

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Autor principal: Ren, Dong-mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379484/
https://www.ncbi.nlm.nih.gov/pubmed/22719682
http://dx.doi.org/10.1107/S1600536812023057
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author Ren, Dong-mei
author_facet Ren, Dong-mei
author_sort Ren, Dong-mei
collection PubMed
description In the title compound, C(10)H(9)Cl(2)NO(3), the dihedral angle between the benzene ring and the plane of the nitro group is 39.1 (1)°, while that between the benzene ring and the plane through the three C and two Cl atoms of the dichloro­all­yloxy unit is 40.1 (1)°. In the crystal, C—H⋯O hydrogen bonds to the nitro groups form chains along the b axis. These chains are linked by inversion-related pairs of Cl⋯O inter­actions at a distance of 3.060 (3) Å, forming sheets approximately parallel to [-201] and generating R (2) (2)(18) rings. π–π contacts between benzene rings in adjacent sheets, with centroid–centroid distances of 3.671 (2) Å, stack mol­ecules along c.
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spelling pubmed-33794842012-06-20 1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene Ren, Dong-mei Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(10)H(9)Cl(2)NO(3), the dihedral angle between the benzene ring and the plane of the nitro group is 39.1 (1)°, while that between the benzene ring and the plane through the three C and two Cl atoms of the dichloro­all­yloxy unit is 40.1 (1)°. In the crystal, C—H⋯O hydrogen bonds to the nitro groups form chains along the b axis. These chains are linked by inversion-related pairs of Cl⋯O inter­actions at a distance of 3.060 (3) Å, forming sheets approximately parallel to [-201] and generating R (2) (2)(18) rings. π–π contacts between benzene rings in adjacent sheets, with centroid–centroid distances of 3.671 (2) Å, stack mol­ecules along c. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379484/ /pubmed/22719682 http://dx.doi.org/10.1107/S1600536812023057 Text en © Dong-mei Ren 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ren, Dong-mei
1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene
title 1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene
title_full 1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene
title_fullStr 1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene
title_full_unstemmed 1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene
title_short 1-(3,3-Dichloro­all­yloxy)-4-methyl-2-nitro­benzene
title_sort 1-(3,3-dichloro­all­yloxy)-4-methyl-2-nitro­benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379484/
https://www.ncbi.nlm.nih.gov/pubmed/22719682
http://dx.doi.org/10.1107/S1600536812023057
work_keys_str_mv AT rendongmei 133dichloroallyloxy4methyl2nitrobenzene