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3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate

In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (−)·H(2)O, the tetra­methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol­ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The...

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Detalles Bibliográficos
Autores principales: Zhang, Ke-Jie, Zhang, Yan-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379486/
https://www.ncbi.nlm.nih.gov/pubmed/22719684
http://dx.doi.org/10.1107/S1600536812023318
Descripción
Sumario:In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (−)·H(2)O, the tetra­methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol­ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water mol­ecule are linked by O—H⋯O and N—H⋯O hydrogen bonds into a sheet parallel to the bc plane. π–π stacking between phenanthroline ring systems is observed in the crystal structure, the centroid–centroid distance being 3.4745 (6) Å.