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3,4,7,8-Tetramethyl-1,10-phenanthrolin-1-ium nitrate monohydrate
In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (−)·H(2)O, the tetramethyl-1,10-phenanthrolinium cations, nitrate anions and lattice water molecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379486/ https://www.ncbi.nlm.nih.gov/pubmed/22719684 http://dx.doi.org/10.1107/S1600536812023318 |
Sumario: | In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (−)·H(2)O, the tetramethyl-1,10-phenanthrolinium cations, nitrate anions and lattice water molecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water molecule are linked by O—H⋯O and N—H⋯O hydrogen bonds into a sheet parallel to the bc plane. π–π stacking between phenanthroline ring systems is observed in the crystal structure, the centroid–centroid distance being 3.4745 (6) Å. |
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