3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate

In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (−)·H(2)O, the tetra­methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol­ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The...

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Detalles Bibliográficos
Autores principales: Zhang, Ke-Jie, Zhang, Yan-Fang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379486/
https://www.ncbi.nlm.nih.gov/pubmed/22719684
http://dx.doi.org/10.1107/S1600536812023318
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author Zhang, Ke-Jie
Zhang, Yan-Fang
author_facet Zhang, Ke-Jie
Zhang, Yan-Fang
author_sort Zhang, Ke-Jie
collection PubMed
description In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (−)·H(2)O, the tetra­methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol­ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water mol­ecule are linked by O—H⋯O and N—H⋯O hydrogen bonds into a sheet parallel to the bc plane. π–π stacking between phenanthroline ring systems is observed in the crystal structure, the centroid–centroid distance being 3.4745 (6) Å.
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spelling pubmed-33794862012-06-20 3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate Zhang, Ke-Jie Zhang, Yan-Fang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the crystal of the title compound, C(16)H(17)N(2) (+)·NO(3) (−)·H(2)O, the tetra­methyl-1,10-phenanthrolinium cations, nitrate anions and lattice water mol­ecules are all located on a mirror plane with the methyl H atoms of the cation equally disordered over two sites about the mirror plane. The cation, anion and water mol­ecule are linked by O—H⋯O and N—H⋯O hydrogen bonds into a sheet parallel to the bc plane. π–π stacking between phenanthroline ring systems is observed in the crystal structure, the centroid–centroid distance being 3.4745 (6) Å. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379486/ /pubmed/22719684 http://dx.doi.org/10.1107/S1600536812023318 Text en © Zhang and Zhang 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhang, Ke-Jie
Zhang, Yan-Fang
3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate
title 3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate
title_full 3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate
title_fullStr 3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate
title_full_unstemmed 3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate
title_short 3,4,7,8-Tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate
title_sort 3,4,7,8-tetra­methyl-1,10-phenanthrolin-1-ium nitrate monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379486/
https://www.ncbi.nlm.nih.gov/pubmed/22719684
http://dx.doi.org/10.1107/S1600536812023318
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