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1-(4-Carboxybutan-2-ylidene)-4-phenylthiosemicarbazide
The molecule of the title compound, C(12)H(15)N(3)O(2)S, which belongs to the family of thiosemicarbazones, containing an acid group, adopts a semi-closed conformation with an intramolecular N—H⋯N hydrogen bond. In the crystal, molecules are linked by strong N—H⋯O and O—H⋯S hydrogen bonds between...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379498/ https://www.ncbi.nlm.nih.gov/pubmed/22719696 http://dx.doi.org/10.1107/S1600536812023793 |
Sumario: | The molecule of the title compound, C(12)H(15)N(3)O(2)S, which belongs to the family of thiosemicarbazones, containing an acid group, adopts a semi-closed conformation with an intramolecular N—H⋯N hydrogen bond. In the crystal, molecules are linked by strong N—H⋯O and O—H⋯S hydrogen bonds between the acid group and thiosemicarbazone unit, with one additional intermolecular hydrogen C—H⋯O interaction. These three interactions form R (2) (2)(8) and a R (2) (1)(7) rings and the molecules related by the c-glide plane are linked into a zigzag chain along [001]. |
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