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3-O-Methyl-1-isomangostin
In the title xanthone derivative [systematic name: 9-hydroxy-5,10-dimethoxy-2,2-dimethyl-11-(3-methylbut-2-en-1-yl)-2,3,4,12-tetrahydro-1,7-dioxatetraphen-12-one], C(25)H(28)O(6), the xanthone ring system is roughly planar, with an r.m.s. deviation of 0.1038 (1) Å. The chromane ring is in a hal...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379502/ https://www.ncbi.nlm.nih.gov/pubmed/22719700 http://dx.doi.org/10.1107/S1600536812023409 |
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author | Boonnak, Nawong Chantrapromma, Suchada Fun, Hoong-Kun |
author_facet | Boonnak, Nawong Chantrapromma, Suchada Fun, Hoong-Kun |
author_sort | Boonnak, Nawong |
collection | PubMed |
description | In the title xanthone derivative [systematic name: 9-hydroxy-5,10-dimethoxy-2,2-dimethyl-11-(3-methylbut-2-en-1-yl)-2,3,4,12-tetrahydro-1,7-dioxatetraphen-12-one], C(25)H(28)O(6), the xanthone ring system is roughly planar, with an r.m.s. deviation of 0.1038 (1) Å. The chromane ring is in a half-chair conformation and the 3-methylbut-2-enyl substituent is axially attached with an (+)-anticlinal conformation. Two weak intramolecular C—H⋯O interactions generate two S(6) ring motifs. In the crystal, molecules are linked into ribbons along the c axis by O—H⋯O and weak C—H⋯O hydrogen bonds. A π–π interaction, with a centroid–centroid distance of 3.5413 (8) Å, is also observed. |
format | Online Article Text |
id | pubmed-3379502 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33795022012-06-20 3-O-Methyl-1-isomangostin Boonnak, Nawong Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title xanthone derivative [systematic name: 9-hydroxy-5,10-dimethoxy-2,2-dimethyl-11-(3-methylbut-2-en-1-yl)-2,3,4,12-tetrahydro-1,7-dioxatetraphen-12-one], C(25)H(28)O(6), the xanthone ring system is roughly planar, with an r.m.s. deviation of 0.1038 (1) Å. The chromane ring is in a half-chair conformation and the 3-methylbut-2-enyl substituent is axially attached with an (+)-anticlinal conformation. Two weak intramolecular C—H⋯O interactions generate two S(6) ring motifs. In the crystal, molecules are linked into ribbons along the c axis by O—H⋯O and weak C—H⋯O hydrogen bonds. A π–π interaction, with a centroid–centroid distance of 3.5413 (8) Å, is also observed. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379502/ /pubmed/22719700 http://dx.doi.org/10.1107/S1600536812023409 Text en © Boonnak et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Boonnak, Nawong Chantrapromma, Suchada Fun, Hoong-Kun 3-O-Methyl-1-isomangostin |
title | 3-O-Methyl-1-isomangostin |
title_full | 3-O-Methyl-1-isomangostin |
title_fullStr | 3-O-Methyl-1-isomangostin |
title_full_unstemmed | 3-O-Methyl-1-isomangostin |
title_short | 3-O-Methyl-1-isomangostin |
title_sort | 3-o-methyl-1-isomangostin |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379502/ https://www.ncbi.nlm.nih.gov/pubmed/22719700 http://dx.doi.org/10.1107/S1600536812023409 |
work_keys_str_mv | AT boonnaknawong 3omethyl1isomangostin AT chantraprommasuchada 3omethyl1isomangostin AT funhoongkun 3omethyl1isomangostin |