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3-O-Methyl-1-isomangostin

In the title xanthone derivative [systematic name: 9-hy­droxy-5,10-dimeth­oxy-2,2-dimethyl-11-(3-methyl­but-2-en-1-yl)-2,3,4,12-tetra­hydro-1,7-dioxatetra­phen-12-one], C(25)H(28)O(6), the xanthone ring system is roughly planar, with an r.m.s. deviation of 0.1038 (1) Å. The chromane ring is in a hal...

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Detalles Bibliográficos
Autores principales: Boonnak, Nawong, Chantrapromma, Suchada, Fun, Hoong-Kun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379502/
https://www.ncbi.nlm.nih.gov/pubmed/22719700
http://dx.doi.org/10.1107/S1600536812023409
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author Boonnak, Nawong
Chantrapromma, Suchada
Fun, Hoong-Kun
author_facet Boonnak, Nawong
Chantrapromma, Suchada
Fun, Hoong-Kun
author_sort Boonnak, Nawong
collection PubMed
description In the title xanthone derivative [systematic name: 9-hy­droxy-5,10-dimeth­oxy-2,2-dimethyl-11-(3-methyl­but-2-en-1-yl)-2,3,4,12-tetra­hydro-1,7-dioxatetra­phen-12-one], C(25)H(28)O(6), the xanthone ring system is roughly planar, with an r.m.s. deviation of 0.1038 (1) Å. The chromane ring is in a half-chair conformation and the 3-methyl­but-2-enyl substituent is axially attached with an (+)-anti­clinal conformation. Two weak intra­molecular C—H⋯O inter­actions generate two S(6) ring motifs. In the crystal, mol­ecules are linked into ribbons along the c axis by O—H⋯O and weak C—H⋯O hydrogen bonds. A π–π inter­action, with a centroid–centroid distance of 3.5413 (8) Å, is also observed.
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spelling pubmed-33795022012-06-20 3-O-Methyl-1-isomangostin Boonnak, Nawong Chantrapromma, Suchada Fun, Hoong-Kun Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title xanthone derivative [systematic name: 9-hy­droxy-5,10-dimeth­oxy-2,2-dimethyl-11-(3-methyl­but-2-en-1-yl)-2,3,4,12-tetra­hydro-1,7-dioxatetra­phen-12-one], C(25)H(28)O(6), the xanthone ring system is roughly planar, with an r.m.s. deviation of 0.1038 (1) Å. The chromane ring is in a half-chair conformation and the 3-methyl­but-2-enyl substituent is axially attached with an (+)-anti­clinal conformation. Two weak intra­molecular C—H⋯O inter­actions generate two S(6) ring motifs. In the crystal, mol­ecules are linked into ribbons along the c axis by O—H⋯O and weak C—H⋯O hydrogen bonds. A π–π inter­action, with a centroid–centroid distance of 3.5413 (8) Å, is also observed. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379502/ /pubmed/22719700 http://dx.doi.org/10.1107/S1600536812023409 Text en © Boonnak et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Boonnak, Nawong
Chantrapromma, Suchada
Fun, Hoong-Kun
3-O-Methyl-1-isomangostin
title 3-O-Methyl-1-isomangostin
title_full 3-O-Methyl-1-isomangostin
title_fullStr 3-O-Methyl-1-isomangostin
title_full_unstemmed 3-O-Methyl-1-isomangostin
title_short 3-O-Methyl-1-isomangostin
title_sort 3-o-methyl-1-isomangostin
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379502/
https://www.ncbi.nlm.nih.gov/pubmed/22719700
http://dx.doi.org/10.1107/S1600536812023409
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