1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene

In the title disulfide, C(16)H(18)S(2), the mol­ecule is twisted about the central S—S bond [the C—S—S—C torsion angle = 93.24 (7)°] and the dihedral angle between the benzene rings is 72.84 (7)°, indicating an almost orthogonal relationship; the methyl groups are orientated to the same side of the...

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Autores principales: Tayamon, Shahedeh, Ravoof, Thahira Begum S. A., Tahir, Mohamed Ibrahim Mohamed, Crouse, Karen A., Tiekink, Edward R. T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379504/
https://www.ncbi.nlm.nih.gov/pubmed/22719702
http://dx.doi.org/10.1107/S160053681202418X
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author Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_facet Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
author_sort Tayamon, Shahedeh
collection PubMed
description In the title disulfide, C(16)H(18)S(2), the mol­ecule is twisted about the central S—S bond [the C—S—S—C torsion angle = 93.24 (7)°] and the dihedral angle between the benzene rings is 72.84 (7)°, indicating an almost orthogonal relationship; the methyl groups are orientated to the same side of the mol­ecule. The crystal packing features C—H⋯.π inter­actions which consolidate a three-dimensional architecture.
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spelling pubmed-33795042012-06-20 1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene Tayamon, Shahedeh Ravoof, Thahira Begum S. A. Tahir, Mohamed Ibrahim Mohamed Crouse, Karen A. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title disulfide, C(16)H(18)S(2), the mol­ecule is twisted about the central S—S bond [the C—S—S—C torsion angle = 93.24 (7)°] and the dihedral angle between the benzene rings is 72.84 (7)°, indicating an almost orthogonal relationship; the methyl groups are orientated to the same side of the mol­ecule. The crystal packing features C—H⋯.π inter­actions which consolidate a three-dimensional architecture. International Union of Crystallography 2012-05-31 /pmc/articles/PMC3379504/ /pubmed/22719702 http://dx.doi.org/10.1107/S160053681202418X Text en © Tayamon et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tayamon, Shahedeh
Ravoof, Thahira Begum S. A.
Tahir, Mohamed Ibrahim Mohamed
Crouse, Karen A.
Tiekink, Edward R. T.
1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene
title 1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene
title_full 1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene
title_fullStr 1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene
title_full_unstemmed 1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene
title_short 1-Methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene
title_sort 1-methyl-2-({[(2-methyl­phen­yl)meth­yl]disulfan­yl}meth­yl)benzene
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3379504/
https://www.ncbi.nlm.nih.gov/pubmed/22719702
http://dx.doi.org/10.1107/S160053681202418X
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