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Carbohydrate-auxiliary assisted preparation of enantiopure 1,2-oxazine derivatives and aminopolyols

An approach to enantiopure hydroxylated 2H-1,2-oxazine derivatives is presented utilizing the [3 + 3] cyclisation of lithiated alkoxyallenes and an L-erythrose-derived N-glycosyl nitrone as precursors. This key step proceeded only with moderate diastereoselectivity, but allowed entry into both enant...

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Detalles Bibliográficos
Autores principales:	Jasiński, Marcin, Lentz, Dieter, Reissig, Hans-Ulrich
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Beilstein-Institut 2012
Materias:	Full Research Paper
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3388852/ https://www.ncbi.nlm.nih.gov/pubmed/23015812 http://dx.doi.org/10.3762/bjoc.8.74

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