Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3)

Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3), crystallizes with four formula units in the space group Cmcm in the KCuZrS(3) structure type. There is one crystallographic­ally independent Th, Tl, and Cu atom at a site of symmetry 2/m.., m2m, and m2m, respectively. There are two crystal...

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Detalles Bibliográficos
Autores principales: Koscielski, Lukasz A., Ibers, James A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393138/
https://www.ncbi.nlm.nih.gov/pubmed/22807695
http://dx.doi.org/10.1107/S1600536812026669
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author Koscielski, Lukasz A.
Ibers, James A.
author_facet Koscielski, Lukasz A.
Ibers, James A.
author_sort Koscielski, Lukasz A.
collection PubMed
description Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3), crystallizes with four formula units in the space group Cmcm in the KCuZrS(3) structure type. There is one crystallographic­ally independent Th, Tl, and Cu atom at a site of symmetry 2/m.., m2m, and m2m, respectively. There are two crystallographically independent Se atoms at sites of symmetry m.. and m2m. The structure consists of sheets of edge-sharing ThSe(6) octa­hedra and CuSe(4) tetra­hedra stacked parallel to the (010) face, separated by layers filled with chains of Tl running parallel to [100]. Each Tl is coordinated by a trigonal prism of Se atoms.
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spelling pubmed-33931382012-07-17 Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3) Koscielski, Lukasz A. Ibers, James A. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3), crystallizes with four formula units in the space group Cmcm in the KCuZrS(3) structure type. There is one crystallographic­ally independent Th, Tl, and Cu atom at a site of symmetry 2/m.., m2m, and m2m, respectively. There are two crystallographically independent Se atoms at sites of symmetry m.. and m2m. The structure consists of sheets of edge-sharing ThSe(6) octa­hedra and CuSe(4) tetra­hedra stacked parallel to the (010) face, separated by layers filled with chains of Tl running parallel to [100]. Each Tl is coordinated by a trigonal prism of Se atoms. International Union of Crystallography 2012-06-20 /pmc/articles/PMC3393138/ /pubmed/22807695 http://dx.doi.org/10.1107/S1600536812026669 Text en © Koscielski and Ibers 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Koscielski, Lukasz A.
Ibers, James A.
Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3)
title Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3)
title_full Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3)
title_fullStr Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3)
title_full_unstemmed Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3)
title_short Thallium(I) copper(I) thorium(IV) tris­elenide, TlCuThSe(3)
title_sort thallium(i) copper(i) thorium(iv) tris­elenide, tlcuthse(3)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393138/
https://www.ncbi.nlm.nih.gov/pubmed/22807695
http://dx.doi.org/10.1107/S1600536812026669
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