K(2)V(2)O(2)(AsO(4))(2)

The vanadium oxide arsenate with formula K(2)V(2)O(2)(AsO(4))(2), dipotassium divanadium(IV) dioxide diarsenate, has been synthesized by solid-state reaction in an evacuated silica ampoule. Its structure is isotypic with K(2)V(2)O(2)(PO(4))(2). The framework is built up from corner-sharing VO(6) oct...

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Detalles Bibliográficos
Autores principales: Belkhiri, Sabrina, Mezaoui, Djillali, Roisnel, Thierry
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393139/
https://www.ncbi.nlm.nih.gov/pubmed/22807696
http://dx.doi.org/10.1107/S1600536812027183
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author Belkhiri, Sabrina
Mezaoui, Djillali
Roisnel, Thierry
author_facet Belkhiri, Sabrina
Mezaoui, Djillali
Roisnel, Thierry
author_sort Belkhiri, Sabrina
collection PubMed
description The vanadium oxide arsenate with formula K(2)V(2)O(2)(AsO(4))(2), dipotassium divanadium(IV) dioxide diarsenate, has been synthesized by solid-state reaction in an evacuated silica ampoule. Its structure is isotypic with K(2)V(2)O(2)(PO(4))(2). The framework is built up from corner-sharing VO(6) octa­hedra and AsO(4) tetra­hedra, creating an infinite [VAsO(8)](∞) chain running along the a- and c-axis directions. The K(+) cations are located in hexa­gonal tunnels, which are delimited by the connection of the [VAsO(8)](∞) chains.
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spelling pubmed-33931392012-07-17 K(2)V(2)O(2)(AsO(4))(2) Belkhiri, Sabrina Mezaoui, Djillali Roisnel, Thierry Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The vanadium oxide arsenate with formula K(2)V(2)O(2)(AsO(4))(2), dipotassium divanadium(IV) dioxide diarsenate, has been synthesized by solid-state reaction in an evacuated silica ampoule. Its structure is isotypic with K(2)V(2)O(2)(PO(4))(2). The framework is built up from corner-sharing VO(6) octa­hedra and AsO(4) tetra­hedra, creating an infinite [VAsO(8)](∞) chain running along the a- and c-axis directions. The K(+) cations are located in hexa­gonal tunnels, which are delimited by the connection of the [VAsO(8)](∞) chains. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393139/ /pubmed/22807696 http://dx.doi.org/10.1107/S1600536812027183 Text en © Belkhiri et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Belkhiri, Sabrina
Mezaoui, Djillali
Roisnel, Thierry
K(2)V(2)O(2)(AsO(4))(2)
title K(2)V(2)O(2)(AsO(4))(2)
title_full K(2)V(2)O(2)(AsO(4))(2)
title_fullStr K(2)V(2)O(2)(AsO(4))(2)
title_full_unstemmed K(2)V(2)O(2)(AsO(4))(2)
title_short K(2)V(2)O(2)(AsO(4))(2)
title_sort k(2)v(2)o(2)(aso(4))(2)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393139/
https://www.ncbi.nlm.nih.gov/pubmed/22807696
http://dx.doi.org/10.1107/S1600536812027183
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AT mezaouidjillali k2v2o2aso42
AT roisnelthierry k2v2o2aso42

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