NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3)

The solid solution, sodium [iron(III)/manganese(II)] tris­(orthophosphate), Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3), was obtained using a flux method. Its crystal structure is related to that of NASICON-type compounds. The [(Mn/Fe)(2)(PO(4))(3)] framework is built up from an (Mn/Fe)O(6) octa­hedron (site sy...

Descripción completa

Detalles Bibliográficos
Autores principales: Yatskin, Michael M., Strutynska, Nataliya Yu., Baumer, Vyacheslav N., Ogorodnyk, Ivan V., Slobodyanik, Nikolay S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393140/
https://www.ncbi.nlm.nih.gov/pubmed/22807697
http://dx.doi.org/10.1107/S1600536812027584
_version_ 1782237680387489792
author Yatskin, Michael M.
Strutynska, Nataliya Yu.
Baumer, Vyacheslav N.
Ogorodnyk, Ivan V.
Slobodyanik, Nikolay S.
author_facet Yatskin, Michael M.
Strutynska, Nataliya Yu.
Baumer, Vyacheslav N.
Ogorodnyk, Ivan V.
Slobodyanik, Nikolay S.
author_sort Yatskin, Michael M.
collection PubMed
description The solid solution, sodium [iron(III)/manganese(II)] tris­(orthophosphate), Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3), was obtained using a flux method. Its crystal structure is related to that of NASICON-type compounds. The [(Mn/Fe)(2)(PO(4))(3)] framework is built up from an (Mn/Fe)O(6) octa­hedron (site symmetry 3.), with a mixed Mn/Fe occupancy, and a PO(4) tetra­hedron (site symmetry .2). The Na(+) cations are distributed over two partially occupied sites in the cavities of the framework. One Na(+) cation (site symmetry -3.) is surrounded by six O atoms, whereas the other Na(+) cation (site symmetry .2) is surrounded by eight O atoms.
format Online
Article
Text
id pubmed-3393140
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33931402012-07-17 NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3) Yatskin, Michael M. Strutynska, Nataliya Yu. Baumer, Vyacheslav N. Ogorodnyk, Ivan V. Slobodyanik, Nikolay S. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The solid solution, sodium [iron(III)/manganese(II)] tris­(orthophosphate), Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3), was obtained using a flux method. Its crystal structure is related to that of NASICON-type compounds. The [(Mn/Fe)(2)(PO(4))(3)] framework is built up from an (Mn/Fe)O(6) octa­hedron (site symmetry 3.), with a mixed Mn/Fe occupancy, and a PO(4) tetra­hedron (site symmetry .2). The Na(+) cations are distributed over two partially occupied sites in the cavities of the framework. One Na(+) cation (site symmetry -3.) is surrounded by six O atoms, whereas the other Na(+) cation (site symmetry .2) is surrounded by eight O atoms. International Union of Crystallography 2012-06-23 /pmc/articles/PMC3393140/ /pubmed/22807697 http://dx.doi.org/10.1107/S1600536812027584 Text en © Yatskin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Yatskin, Michael M.
Strutynska, Nataliya Yu.
Baumer, Vyacheslav N.
Ogorodnyk, Ivan V.
Slobodyanik, Nikolay S.
NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3)
title NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3)
title_full NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3)
title_fullStr NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3)
title_full_unstemmed NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3)
title_short NASICON-related Na(3.4)Mn(0.4)Fe(1.6)(PO(4))(3)
title_sort nasicon-related na(3.4)mn(0.4)fe(1.6)(po(4))(3)
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393140/
https://www.ncbi.nlm.nih.gov/pubmed/22807697
http://dx.doi.org/10.1107/S1600536812027584
work_keys_str_mv AT yatskinmichaelm nasiconrelatedna34mn04fe16po43
AT strutynskanataliyayu nasiconrelatedna34mn04fe16po43
AT baumervyacheslavn nasiconrelatedna34mn04fe16po43
AT ogorodnykivanv nasiconrelatedna34mn04fe16po43
AT slobodyaniknikolays nasiconrelatedna34mn04fe16po43

Ejemplares similares