cis-Diamminedichloridoplatinum(II) N,N-dimethyl­formamide monosolvate

In the title compound, cis-[PtCl(2)(NH(3))(2)]·C(3)H(7)NO, the metal complex mol­ecules are stacked parallel to the b axis, forming close Pt⋯Pt inter­actions of 3.4071 (7) and 3.5534 (8) Å and weak N—H⋯Cl hydrogen bonds between the ammine ligand and the Cl atoms of the neighboring complex. Conventio...

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Detalles Bibliográficos
Autores principales: Johnston, Dean H., Miller, Nathanael A., Tackett, Cory B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393146/
https://www.ncbi.nlm.nih.gov/pubmed/22807714
http://dx.doi.org/10.1107/S1600536812024014
Descripción
Sumario:In the title compound, cis-[PtCl(2)(NH(3))(2)]·C(3)H(7)NO, the metal complex mol­ecules are stacked parallel to the b axis, forming close Pt⋯Pt inter­actions of 3.4071 (7) and 3.5534 (8) Å and weak N—H⋯Cl hydrogen bonds between the ammine ligand and the Cl atoms of the neighboring complex. Conventional N—H⋯O hydrogen bonds are formed between ammine ligands and the O atom of adjacent N,N-dimethyl­formamide mol­ecules. The crystal was found to be a split crystal and was analyzed using two domains related by a rotation of ca 4.4° about the reciprocal axis (−0.351 1.000 0.742) and refined to give a minor component fraction of 0.084 (6).

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