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Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carbo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393147/ https://www.ncbi.nlm.nih.gov/pubmed/22807715 http://dx.doi.org/10.1107/S1600536812019642 |
Sumario: | The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxylate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent molecules are hydrogen bonded within the chain along the c axis. |
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