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Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate]

The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethyl­silanedi­yl)dibenzoate ligands and two half 1,1′-(1,4-phenyl­ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carbo...

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Detalles Bibliográficos
Autores principales: Huang, Guohui, Bei, Yiling
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393147/
https://www.ncbi.nlm.nih.gov/pubmed/22807715
http://dx.doi.org/10.1107/S1600536812019642
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author Huang, Guohui
Bei, Yiling
author_facet Huang, Guohui
Bei, Yiling
author_sort Huang, Guohui
collection PubMed
description The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethyl­silanedi­yl)dibenzoate ligands and two half 1,1′-(1,4-phenyl­ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxyl­ate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent mol­ecules are hydrogen bonded within the chain along the c axis.
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spelling pubmed-33931472012-07-17 Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate] Huang, Guohui Bei, Yiling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethyl­silanedi­yl)dibenzoate ligands and two half 1,1′-(1,4-phenyl­ene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxyl­ate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent mol­ecules are hydrogen bonded within the chain along the c axis. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393147/ /pubmed/22807715 http://dx.doi.org/10.1107/S1600536812019642 Text en © Huang and Bei 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Huang, Guohui
Bei, Yiling
Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate]
title Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate]
title_full Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate]
title_fullStr Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate]
title_full_unstemmed Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate]
title_short Poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1H-imidazole]­zinc] monohydrate]
title_sort poly[[[μ-3,3′-(dimethyl­silanedi­yl)dibenzoato][μ-1,1′-(1,4-phenyl­ene)di-1h-imidazole]­zinc] monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393147/
https://www.ncbi.nlm.nih.gov/pubmed/22807715
http://dx.doi.org/10.1107/S1600536812019642
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AT beiyiling polym33dimethylsilanediyldibenzoatom1114phenylenedi1himidazolezincmonohydrate