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Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate]
The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carbo...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393147/ https://www.ncbi.nlm.nih.gov/pubmed/22807715 http://dx.doi.org/10.1107/S1600536812019642 |
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author | Huang, Guohui Bei, Yiling |
author_facet | Huang, Guohui Bei, Yiling |
author_sort | Huang, Guohui |
collection | PubMed |
description | The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxylate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent molecules are hydrogen bonded within the chain along the c axis. |
format | Online Article Text |
id | pubmed-3393147 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931472012-07-17 Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate] Huang, Guohui Bei, Yiling Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, {[Zn(C(16)H(16)O(4)Si)(C(12)H(10)N(4))]·H(2)O}(n), consists of one Zn(II) ion, two half 3,3′-(dimethylsilanediyl)dibenzoate ligands and two half 1,1′-(1,4-phenylene)di-1H-imidazole ligands. The Zn(II) ion is four-coordinated by two O atoms from two carboxlate ligands, two N atoms from two imidazole ligands. Two Zn(II) ions are bridged by two carboxylate groups in chelating mode, generating a binuclear secondary building unit (SBU), which is further coordinated by two N atoms from two imidazole ligands in monodentate mode. Thus, the binuclear SBUs are further bridged by imidazole ligands in two different directions, giving rise to a chain. The water solvent molecules are hydrogen bonded within the chain along the c axis. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393147/ /pubmed/22807715 http://dx.doi.org/10.1107/S1600536812019642 Text en © Huang and Bei 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Huang, Guohui Bei, Yiling Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate] |
title | Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate] |
title_full | Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate] |
title_fullStr | Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate] |
title_full_unstemmed | Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate] |
title_short | Poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1H-imidazole]zinc] monohydrate] |
title_sort | poly[[[μ-3,3′-(dimethylsilanediyl)dibenzoato][μ-1,1′-(1,4-phenylene)di-1h-imidazole]zinc] monohydrate] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393147/ https://www.ncbi.nlm.nih.gov/pubmed/22807715 http://dx.doi.org/10.1107/S1600536812019642 |
work_keys_str_mv | AT huangguohui polym33dimethylsilanediyldibenzoatom1114phenylenedi1himidazolezincmonohydrate AT beiyiling polym33dimethylsilanediyldibenzoatom1114phenylenedi1himidazolezincmonohydrate |