Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)

In the title compound, [Co(NCS)(2)(C(11)H(9)N(3)O)(2)(H(2)O)(2)], the octa­hedrally coordinated Co(II) ion lies on a crystallographic inversion center and is bound by two isothio­cyanate ligands, two aqua ligands and two N-(pyridin-4-yl)isonicotinamide (4-pina) ligands. The dihedral angle between th...

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Detalles Bibliográficos
Autores principales: Uebler, Jacob W., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393148/
https://www.ncbi.nlm.nih.gov/pubmed/22807716
http://dx.doi.org/10.1107/S1600536812024105
Descripción
Sumario:In the title compound, [Co(NCS)(2)(C(11)H(9)N(3)O)(2)(H(2)O)(2)], the octa­hedrally coordinated Co(II) ion lies on a crystallographic inversion center and is bound by two isothio­cyanate ligands, two aqua ligands and two N-(pyridin-4-yl)isonicotinamide (4-pina) ligands. The dihedral angle between the aromatic rings in the 4-pina ligand is 8.98 (11)°. In the crystal, the individual mol­ecular units are aggregated in three dimensions by O—H⋯N, O—H⋯S and N—H⋯S hydrogen-bonding pathways.

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