Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)

In the title compound, [Co(NCS)(2)(C(11)H(9)N(3)O)(2)(H(2)O)(2)], the octa­hedrally coordinated Co(II) ion lies on a crystallographic inversion center and is bound by two isothio­cyanate ligands, two aqua ligands and two N-(pyridin-4-yl)isonicotinamide (4-pina) ligands. The dihedral angle between th...

Descripción completa

Detalles Bibliográficos
Autores principales: Uebler, Jacob W., LaDuca, Robert L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393148/
https://www.ncbi.nlm.nih.gov/pubmed/22807716
http://dx.doi.org/10.1107/S1600536812024105
_version_ 1782237682213060608
author Uebler, Jacob W.
LaDuca, Robert L.
author_facet Uebler, Jacob W.
LaDuca, Robert L.
author_sort Uebler, Jacob W.
collection PubMed
description In the title compound, [Co(NCS)(2)(C(11)H(9)N(3)O)(2)(H(2)O)(2)], the octa­hedrally coordinated Co(II) ion lies on a crystallographic inversion center and is bound by two isothio­cyanate ligands, two aqua ligands and two N-(pyridin-4-yl)isonicotinamide (4-pina) ligands. The dihedral angle between the aromatic rings in the 4-pina ligand is 8.98 (11)°. In the crystal, the individual mol­ecular units are aggregated in three dimensions by O—H⋯N, O—H⋯S and N—H⋯S hydrogen-bonding pathways.
format Online
Article
Text
id pubmed-3393148
institution National Center for Biotechnology Information
language English
publishDate 2012
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-33931482012-07-17 Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II) Uebler, Jacob W. LaDuca, Robert L. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Co(NCS)(2)(C(11)H(9)N(3)O)(2)(H(2)O)(2)], the octa­hedrally coordinated Co(II) ion lies on a crystallographic inversion center and is bound by two isothio­cyanate ligands, two aqua ligands and two N-(pyridin-4-yl)isonicotinamide (4-pina) ligands. The dihedral angle between the aromatic rings in the 4-pina ligand is 8.98 (11)°. In the crystal, the individual mol­ecular units are aggregated in three dimensions by O—H⋯N, O—H⋯S and N—H⋯S hydrogen-bonding pathways. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393148/ /pubmed/22807716 http://dx.doi.org/10.1107/S1600536812024105 Text en © Uebler and LaDuca 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Uebler, Jacob W.
LaDuca, Robert L.
Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)
title Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)
title_full Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)
title_fullStr Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)
title_full_unstemmed Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)
title_short Diaqua­bis­[N-(pyridin-4-yl)isonicotin­amide-κN]bis­(thio­cyanato-κN)cobalt(II)
title_sort diaqua­bis­[n-(pyridin-4-yl)isonicotin­amide-κn]bis­(thio­cyanato-κn)cobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393148/
https://www.ncbi.nlm.nih.gov/pubmed/22807716
http://dx.doi.org/10.1107/S1600536812024105
work_keys_str_mv AT ueblerjacobw diaquabisnpyridin4ylisonicotinamideknbisthiocyanatokncobaltii
AT laducarobertl diaquabisnpyridin4ylisonicotinamideknbisthiocyanatokncobaltii

Ejemplares similares