catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′]

In the title compound, [MoPb(C(5)H(5))(CH(3)COO)(CO)(3)], the Pb(II) atom is coordinated pyramidally via the Mo(0) atom of a {Cp(CO)(3)Mo} (Cp = cyclo­penta­dien­yl) fragment [Pb—Mo = 3.0589 (5) Å] and a chelating acetate (Ac) group. Additionally, the [{Cp(CO)(3)Mo}PbAc] units are linked along [100]...

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Detalles Bibliográficos
Autores principales: Gerdes, Eberhard, Merzweiler, Kurt
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393150/
https://www.ncbi.nlm.nih.gov/pubmed/22807718
http://dx.doi.org/10.1107/S1600536812024737
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author Gerdes, Eberhard
Merzweiler, Kurt
author_facet Gerdes, Eberhard
Merzweiler, Kurt
author_sort Gerdes, Eberhard
collection PubMed
description In the title compound, [MoPb(C(5)H(5))(CH(3)COO)(CO)(3)], the Pb(II) atom is coordinated pyramidally via the Mo(0) atom of a {Cp(CO)(3)Mo} (Cp = cyclo­penta­dien­yl) fragment [Pb—Mo = 3.0589 (5) Å] and a chelating acetate (Ac) group. Additionally, the [{Cp(CO)(3)Mo}PbAc] units are linked along [100] by Pb—O(acetate) inter­actions, giving a ladder-type polymeric structure composed of PbCO(2) and Pb(2)O(2) four-membered rings. The {Cp(CO)(3)Mo} units attached to the Pb(II) atom occupy terminal positions at opposite sides of the slightly puckered lead acetate chain. The angle between the Pb—Mo bond vector and the central chain plane is 67.8 (2)°.
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spelling pubmed-33931502012-07-17 catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′] Gerdes, Eberhard Merzweiler, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [MoPb(C(5)H(5))(CH(3)COO)(CO)(3)], the Pb(II) atom is coordinated pyramidally via the Mo(0) atom of a {Cp(CO)(3)Mo} (Cp = cyclo­penta­dien­yl) fragment [Pb—Mo = 3.0589 (5) Å] and a chelating acetate (Ac) group. Additionally, the [{Cp(CO)(3)Mo}PbAc] units are linked along [100] by Pb—O(acetate) inter­actions, giving a ladder-type polymeric structure composed of PbCO(2) and Pb(2)O(2) four-membered rings. The {Cp(CO)(3)Mo} units attached to the Pb(II) atom occupy terminal positions at opposite sides of the slightly puckered lead acetate chain. The angle between the Pb—Mo bond vector and the central chain plane is 67.8 (2)°. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393150/ /pubmed/22807718 http://dx.doi.org/10.1107/S1600536812024737 Text en © Gerdes and Merzweiler 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gerdes, Eberhard
Merzweiler, Kurt
catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′]
title catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′]
title_full catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′]
title_fullStr catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′]
title_full_unstemmed catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′]
title_short catena-Poly[[tricarbonyl-1κ(3) C-(1η(5)-cyclo­penta­dien­yl)lead(II)molyb­denum(0)](Mo—Pb)-μ(3)-acetato-2′:2:2′′κ(4) O:O,O′:O′]
title_sort catena-poly[[tricarbonyl-1κ(3) c-(1η(5)-cyclo­penta­dien­yl)lead(ii)molyb­denum(0)](mo—pb)-μ(3)-acetato-2′:2:2′′κ(4) o:o,o′:o′]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393150/
https://www.ncbi.nlm.nih.gov/pubmed/22807718
http://dx.doi.org/10.1107/S1600536812024737
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