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Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III)
In the title compound, [Cu(C(27)H(26)P(2))(2)][GaCl(4)], the Cu(I) atom in the complex cation is P,P′-chelated by two 1,3-bis(diphenylphosphanyl)propane ligands in a distorted tetrahedral geometry, while the Ga(III) cation is coordinated by four chloride anions in a distorted tetrahedral geomet...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393151/ https://www.ncbi.nlm.nih.gov/pubmed/22807719 http://dx.doi.org/10.1107/S1600536812024269 |
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author | Wang, Nian-Nian Hu, Feng Duan, Tai-Ke Chen, Qun Zhang, Qian-Feng |
author_facet | Wang, Nian-Nian Hu, Feng Duan, Tai-Ke Chen, Qun Zhang, Qian-Feng |
author_sort | Wang, Nian-Nian |
collection | PubMed |
description | In the title compound, [Cu(C(27)H(26)P(2))(2)][GaCl(4)], the Cu(I) atom in the complex cation is P,P′-chelated by two 1,3-bis(diphenylphosphanyl)propane ligands in a distorted tetrahedral geometry, while the Ga(III) cation is coordinated by four chloride anions in a distorted tetrahedral geometry. In the crystal, weak C—H⋯π interactions occur between adjacent complex cations. |
format | Online Article Text |
id | pubmed-3393151 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931512012-07-17 Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III) Wang, Nian-Nian Hu, Feng Duan, Tai-Ke Chen, Qun Zhang, Qian-Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(27)H(26)P(2))(2)][GaCl(4)], the Cu(I) atom in the complex cation is P,P′-chelated by two 1,3-bis(diphenylphosphanyl)propane ligands in a distorted tetrahedral geometry, while the Ga(III) cation is coordinated by four chloride anions in a distorted tetrahedral geometry. In the crystal, weak C—H⋯π interactions occur between adjacent complex cations. International Union of Crystallography 2012-06-02 /pmc/articles/PMC3393151/ /pubmed/22807719 http://dx.doi.org/10.1107/S1600536812024269 Text en © Wang et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Wang, Nian-Nian Hu, Feng Duan, Tai-Ke Chen, Qun Zhang, Qian-Feng Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III) |
title | Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III) |
title_full | Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III) |
title_fullStr | Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III) |
title_full_unstemmed | Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III) |
title_short | Bis[1,3-bis(diphenylphosphanyl)propane]copper(I) tetrachloridogallate(III) |
title_sort | bis[1,3-bis(diphenylphosphanyl)propane]copper(i) tetrachloridogallate(iii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393151/ https://www.ncbi.nlm.nih.gov/pubmed/22807719 http://dx.doi.org/10.1107/S1600536812024269 |
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