Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate

In the title compound, [Cu(C(7)H(7)N(2)O)(C(7)H(8)N(2)O)(H(2)O)]ClO(4)·H(2)O, the Cu(II) ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan­one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic liga...

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Detalles Bibliográficos
Autores principales: Zhong, Baoyun, Li, Shengli, Chen, Guifang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393154/
https://www.ncbi.nlm.nih.gov/pubmed/22807722
http://dx.doi.org/10.1107/S1600536812023872
Descripción
Sumario:In the title compound, [Cu(C(7)H(7)N(2)O)(C(7)H(8)N(2)O)(H(2)O)]ClO(4)·H(2)O, the Cu(II) ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan­one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic ligands are linked by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules and ions are linked by O—H⋯O hydrogen-bonding inter­actions, forming chains along the a axis. The perchlorate O atoms are disordered in a 0.58 (2):0.42 (2) ratio.

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