Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate

In the title compound, [Cu(C(7)H(7)N(2)O)(C(7)H(8)N(2)O)(H(2)O)]ClO(4)·H(2)O, the Cu(II) ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan­one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic liga...

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Detalles Bibliográficos
Autores principales: Zhong, Baoyun, Li, Shengli, Chen, Guifang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393154/
https://www.ncbi.nlm.nih.gov/pubmed/22807722
http://dx.doi.org/10.1107/S1600536812023872
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author Zhong, Baoyun
Li, Shengli
Chen, Guifang
author_facet Zhong, Baoyun
Li, Shengli
Chen, Guifang
author_sort Zhong, Baoyun
collection PubMed
description In the title compound, [Cu(C(7)H(7)N(2)O)(C(7)H(8)N(2)O)(H(2)O)]ClO(4)·H(2)O, the Cu(II) ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan­one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic ligands are linked by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules and ions are linked by O—H⋯O hydrogen-bonding inter­actions, forming chains along the a axis. The perchlorate O atoms are disordered in a 0.58 (2):0.42 (2) ratio.
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spelling pubmed-33931542012-07-17 Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate Zhong, Baoyun Li, Shengli Chen, Guifang Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(C(7)H(7)N(2)O)(C(7)H(8)N(2)O)(H(2)O)]ClO(4)·H(2)O, the Cu(II) ion is five-coordinated by the N atoms from the 1-(pyridin-2-yl)ethanone oximate and 1-(pyridin-2-yl)ethan­one oxime ligands and by the water O atom in a distorted square-pyramidal geometry. The two organic ligands are linked by an intra­molecular O—H⋯O hydrogen bond. In the crystal, mol­ecules and ions are linked by O—H⋯O hydrogen-bonding inter­actions, forming chains along the a axis. The perchlorate O atoms are disordered in a 0.58 (2):0.42 (2) ratio. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393154/ /pubmed/22807722 http://dx.doi.org/10.1107/S1600536812023872 Text en © Zhong et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhong, Baoyun
Li, Shengli
Chen, Guifang
Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate
title Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate
title_full Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate
title_fullStr Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate
title_full_unstemmed Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate
title_short Aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(II) perchlorate mono­hydrate
title_sort aqua[1-(pyridin-2-yl)ethanone oximato][1-(2-pyridin-2-yl)ethanone oxime]­copper(ii) perchlorate mono­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393154/
https://www.ncbi.nlm.nih.gov/pubmed/22807722
http://dx.doi.org/10.1107/S1600536812023872
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AT chenguifang aqua1pyridin2ylethanoneoximato12pyridin2ylethanoneoximecopperiiperchloratemonohydrate

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