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Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4) N:O;κ(4) O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh)
The title structure, [Rh(2)(C(11)H(14)NO)(4)(C(7)H(5)N)(2)], contains a dinuclear Rh complex of point symmetry -4 with an Rh—Rh unit and two benzonitrile ligands located in special positions along the twofold axis passing through -4. Four symmetry-equivalent mesitylacetamidate ligands bridge the Rh—...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393156/ https://www.ncbi.nlm.nih.gov/pubmed/22807724 http://dx.doi.org/10.1107/S1600536812024518 |
| _version_ | 1782237684043874304 |
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| author | Eagle, Cassandra T. Kpogo, Kenneth K. Zink, Landon C. Smith, Albert E. |
| author_facet | Eagle, Cassandra T. Kpogo, Kenneth K. Zink, Landon C. Smith, Albert E. |
| author_sort | Eagle, Cassandra T. |
| collection | PubMed |
| description | The title structure, [Rh(2)(C(11)H(14)NO)(4)(C(7)H(5)N)(2)], contains a dinuclear Rh complex of point symmetry -4 with an Rh—Rh unit and two benzonitrile ligands located in special positions along the twofold axis passing through -4. Four symmetry-equivalent mesitylacetamidate ligands bridge the Rh—Rh unit. Thus, each Rh(II) atom has an approximately octahedral coordination by one Rh [Rh—Rh = 2.4290 (6) Å], two acetamidate O atoms trans to each other [Rh—O = 2.044 (3) Å], two acetamidate N atoms trans to each other [Rh—N = 2.091 (4) Å], and a benzonitrile N atom trans to Rh [Rh—N = 2.222 (3) Å]. The structure is held together by weak van der Waals forces. |
| format | Online Article Text |
| id | pubmed-3393156 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33931562012-07-17 Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4) N:O;κ(4) O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh) Eagle, Cassandra T. Kpogo, Kenneth K. Zink, Landon C. Smith, Albert E. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title structure, [Rh(2)(C(11)H(14)NO)(4)(C(7)H(5)N)(2)], contains a dinuclear Rh complex of point symmetry -4 with an Rh—Rh unit and two benzonitrile ligands located in special positions along the twofold axis passing through -4. Four symmetry-equivalent mesitylacetamidate ligands bridge the Rh—Rh unit. Thus, each Rh(II) atom has an approximately octahedral coordination by one Rh [Rh—Rh = 2.4290 (6) Å], two acetamidate O atoms trans to each other [Rh—O = 2.044 (3) Å], two acetamidate N atoms trans to each other [Rh—N = 2.091 (4) Å], and a benzonitrile N atom trans to Rh [Rh—N = 2.222 (3) Å]. The structure is held together by weak van der Waals forces. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393156/ /pubmed/22807724 http://dx.doi.org/10.1107/S1600536812024518 Text en © Eagle et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Eagle, Cassandra T. Kpogo, Kenneth K. Zink, Landon C. Smith, Albert E. Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4) N:O;κ(4) O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh) |
| title | Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4)
N:O;κ(4)
O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh) |
| title_full | Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4)
N:O;κ(4)
O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh) |
| title_fullStr | Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4)
N:O;κ(4)
O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh) |
| title_full_unstemmed | Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4)
N:O;κ(4)
O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh) |
| title_short | Tetrakis[μ-N-(2,4,6-trimethylphenyl)acetamidato]-κ(4)
N:O;κ(4)
O:N-bis[(benzonitrile-κN)rhodium(II)](Rh—Rh) |
| title_sort | tetrakis[μ-n-(2,4,6-trimethylphenyl)acetamidato]-κ(4)
n:o;κ(4)
o:n-bis[(benzonitrile-κn)rhodium(ii)](rh—rh) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393156/ https://www.ncbi.nlm.nih.gov/pubmed/22807724 http://dx.doi.org/10.1107/S1600536812024518 |
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