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catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]

In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of t...

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Detalles Bibliográficos
Autores principales: Yamin, Bohari M., Ismail, Wafiuddin, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393162/
https://www.ncbi.nlm.nih.gov/pubmed/22807730
http://dx.doi.org/10.1107/S1600536812024932
Descripción
Sumario:In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of the Cu–macrocyclic complex is distorted octa­hedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central Cu(II) atom. The tetrachloridocuprate anion adopts a distorted tetra­hedral geometry. In the crystal, the chain is stabilized by intra- and inter­molecular N—H⋯Cl hydrogen bonds.