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catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido]
In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393162/ https://www.ncbi.nlm.nih.gov/pubmed/22807730 http://dx.doi.org/10.1107/S1600536812024932 |
Sumario: | In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of the Cu–macrocyclic complex is distorted octahedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central Cu(II) atom. The tetrachloridocuprate anion adopts a distorted tetrahedral geometry. In the crystal, the chain is stabilized by intra- and intermolecular N—H⋯Cl hydrogen bonds. |
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