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catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido]
In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of t...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393162/ https://www.ncbi.nlm.nih.gov/pubmed/22807730 http://dx.doi.org/10.1107/S1600536812024932 |
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author | Yamin, Bohari M. Ismail, Wafiuddin Daran, Jean-Claude |
author_facet | Yamin, Bohari M. Ismail, Wafiuddin Daran, Jean-Claude |
author_sort | Yamin, Bohari M. |
collection | PubMed |
description | In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of the Cu–macrocyclic complex is distorted octahedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central Cu(II) atom. The tetrachloridocuprate anion adopts a distorted tetrahedral geometry. In the crystal, the chain is stabilized by intra- and intermolecular N—H⋯Cl hydrogen bonds. |
format | Online Article Text |
id | pubmed-3393162 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931622012-07-17 catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido] Yamin, Bohari M. Ismail, Wafiuddin Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of the Cu–macrocyclic complex is distorted octahedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central Cu(II) atom. The tetrachloridocuprate anion adopts a distorted tetrahedral geometry. In the crystal, the chain is stabilized by intra- and intermolecular N—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393162/ /pubmed/22807730 http://dx.doi.org/10.1107/S1600536812024932 Text en © Yamin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yamin, Bohari M. Ismail, Wafiuddin Daran, Jean-Claude catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido] |
title |
catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido] |
title_full |
catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido] |
title_fullStr |
catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido] |
title_full_unstemmed |
catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido] |
title_short |
catena-Poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(II)]-μ-chlorido-[dichlorocuprate(II)]-μ-chlorido] |
title_sort | catena-poly[[(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-1,7-diene)copper(ii)]-μ-chlorido-[dichlorocuprate(ii)]-μ-chlorido] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393162/ https://www.ncbi.nlm.nih.gov/pubmed/22807730 http://dx.doi.org/10.1107/S1600536812024932 |
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