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catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]

In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of t...

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Autores principales: Yamin, Bohari M., Ismail, Wafiuddin, Daran, Jean-Claude
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393162/
https://www.ncbi.nlm.nih.gov/pubmed/22807730
http://dx.doi.org/10.1107/S1600536812024932
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author Yamin, Bohari M.
Ismail, Wafiuddin
Daran, Jean-Claude
author_facet Yamin, Bohari M.
Ismail, Wafiuddin
Daran, Jean-Claude
author_sort Yamin, Bohari M.
collection PubMed
description In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of the Cu–macrocyclic complex is distorted octa­hedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central Cu(II) atom. The tetrachloridocuprate anion adopts a distorted tetra­hedral geometry. In the crystal, the chain is stabilized by intra- and inter­molecular N—H⋯Cl hydrogen bonds.
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spelling pubmed-33931622012-07-17 catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido] Yamin, Bohari M. Ismail, Wafiuddin Daran, Jean-Claude Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cu(2)Cl(4)(C(16)H(32)N(4))](n), the central Cu(II) anion of the macrocyclic complex cation is weakly linked to two Cl atoms of the tetrachloridocuprate anion with Cu—Cl distances of 3.008 (3) and 3.220 (3) Å, respectively, forming a chain parallel to [10-1]. The geometry of the Cu–macrocyclic complex is distorted octa­hedral with the bridging Cl atoms occupying the axial position at an angle of 173.44 (7)° about the central Cu(II) atom. The tetrachloridocuprate anion adopts a distorted tetra­hedral geometry. In the crystal, the chain is stabilized by intra- and inter­molecular N—H⋯Cl hydrogen bonds. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393162/ /pubmed/22807730 http://dx.doi.org/10.1107/S1600536812024932 Text en © Yamin et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yamin, Bohari M.
Ismail, Wafiuddin
Daran, Jean-Claude
catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]
title catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]
title_full catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]
title_fullStr catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]
title_full_unstemmed catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]
title_short catena-Poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(II)]-μ-chlorido-[dichloro­cuprate(II)]-μ-chlorido]
title_sort catena-poly[[(5,5,7,12,12,14-hexa­methyl-1,4,8,11-tetra­aza­cyclo­tetra­deca-1,7-diene)copper(ii)]-μ-chlorido-[dichloro­cuprate(ii)]-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393162/
https://www.ncbi.nlm.nih.gov/pubmed/22807730
http://dx.doi.org/10.1107/S1600536812024932
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