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Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN (2))methane]nickelate(II)
The title salt, (C(8)H(20)N)[Ni(NCS)(3)(C(10)H(10)N(6))], consists of a tetraethylammonium cation and an anion comprising an octahedral Ni(II) atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The liga...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393163/ https://www.ncbi.nlm.nih.gov/pubmed/22807731 http://dx.doi.org/10.1107/S1600536812024774 |
| Sumario: | The title salt, (C(8)H(20)N)[Ni(NCS)(3)(C(10)H(10)N(6))], consists of a tetraethylammonium cation and an anion comprising an octahedral Ni(II) atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni—N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°. |
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