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Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN (2))methane]nickelate(II)
The title salt, (C(8)H(20)N)[Ni(NCS)(3)(C(10)H(10)N(6))], consists of a tetraethylammonium cation and an anion comprising an octahedral Ni(II) atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The liga...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393163/ https://www.ncbi.nlm.nih.gov/pubmed/22807731 http://dx.doi.org/10.1107/S1600536812024774 |
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| author | Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Jeon, Hee Kyung |
| author_facet | Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Jeon, Hee Kyung |
| author_sort | Lyubartseva, Ganna |
| collection | PubMed |
| description | The title salt, (C(8)H(20)N)[Ni(NCS)(3)(C(10)H(10)N(6))], consists of a tetraethylammonium cation and an anion comprising an octahedral Ni(II) atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni—N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°. |
| format | Online Article Text |
| id | pubmed-3393163 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33931632012-07-17 Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN (2))methane]nickelate(II) Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Jeon, Hee Kyung Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title salt, (C(8)H(20)N)[Ni(NCS)(3)(C(10)H(10)N(6))], consists of a tetraethylammonium cation and an anion comprising an octahedral Ni(II) atom surrounded by three N atoms from a tripodal tris(pyrazol-1-yl)methane ligand, and three thiocyanate ligands, each bound at the N-atom end. The ligand Ni—N distances range from 2.097 (2) to 2.127 (2) Å for the tripodal ligand and from 2.045 (2) to 2.075 (2) Å for the thiocyanate ligands. The dihedral angles between the three pyrazole rings are 59.03 (12), 53.09 (10) and 67.90 (10)°. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393163/ /pubmed/22807731 http://dx.doi.org/10.1107/S1600536812024774 Text en © Lyubartseva et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Lyubartseva, Ganna Parkin, Sean Mallik, Uma Prasad Jeon, Hee Kyung Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN (2))methane]nickelate(II) |
| title | Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN
(2))methane]nickelate(II) |
| title_full | Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN
(2))methane]nickelate(II) |
| title_fullStr | Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN
(2))methane]nickelate(II) |
| title_full_unstemmed | Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN
(2))methane]nickelate(II) |
| title_short | Tetraethylammonium tris(thiocyanato-κN)[tris(1H-pyrazol-1-yl-κN
(2))methane]nickelate(II) |
| title_sort | tetraethylammonium tris(thiocyanato-κn)[tris(1h-pyrazol-1-yl-κn
(2))methane]nickelate(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393163/ https://www.ncbi.nlm.nih.gov/pubmed/22807731 http://dx.doi.org/10.1107/S1600536812024774 |
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