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catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]

In the title compound, [Cd(2)I(4)(C(6)H(14)N(2))(2)](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octa­hedral coordination environment by four N atoms from two cyclo­hexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordin...

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Detalles Bibliográficos
Autores principales: Cui, Sheng-Feng, Wen, Qin-Mei, Zhou, Cheng-He
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393164/
https://www.ncbi.nlm.nih.gov/pubmed/22807732
http://dx.doi.org/10.1107/S1600536812024828
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author Cui, Sheng-Feng
Wen, Qin-Mei
Zhou, Cheng-He
author_facet Cui, Sheng-Feng
Wen, Qin-Mei
Zhou, Cheng-He
author_sort Cui, Sheng-Feng
collection PubMed
description In the title compound, [Cd(2)I(4)(C(6)H(14)N(2))(2)](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octa­hedral coordination environment by four N atoms from two cyclo­hexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetra­hedral coordination environment. Two of the iodido ligands act as bridging ligands connecting Cd(II) ions and forming a one-dimensional polymer along [010]. In the crystal, N—H⋯I hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001).
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spelling pubmed-33931642012-07-17 catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] Cui, Sheng-Feng Wen, Qin-Mei Zhou, Cheng-He Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)I(4)(C(6)H(14)N(2))(2)](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octa­hedral coordination environment by four N atoms from two cyclo­hexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetra­hedral coordination environment. Two of the iodido ligands act as bridging ligands connecting Cd(II) ions and forming a one-dimensional polymer along [010]. In the crystal, N—H⋯I hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001). International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393164/ /pubmed/22807732 http://dx.doi.org/10.1107/S1600536812024828 Text en © Cui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Cui, Sheng-Feng
Wen, Qin-Mei
Zhou, Cheng-He
catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
title catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
title_full catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
title_fullStr catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
title_full_unstemmed catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
title_short catena-Poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
title_sort catena-poly[[trans-bis­(cyclo­hexane-1,2-diamine-κ(2) n,n)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393164/
https://www.ncbi.nlm.nih.gov/pubmed/22807732
http://dx.doi.org/10.1107/S1600536812024828
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