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catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido]
In the title compound, [Cd(2)I(4)(C(6)H(14)N(2))(2)](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octahedral coordination environment by four N atoms from two cyclohexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordin...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393164/ https://www.ncbi.nlm.nih.gov/pubmed/22807732 http://dx.doi.org/10.1107/S1600536812024828 |
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author | Cui, Sheng-Feng Wen, Qin-Mei Zhou, Cheng-He |
author_facet | Cui, Sheng-Feng Wen, Qin-Mei Zhou, Cheng-He |
author_sort | Cui, Sheng-Feng |
collection | PubMed |
description | In the title compound, [Cd(2)I(4)(C(6)H(14)N(2))(2)](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octahedral coordination environment by four N atoms from two cyclohexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetrahedral coordination environment. Two of the iodido ligands act as bridging ligands connecting Cd(II) ions and forming a one-dimensional polymer along [010]. In the crystal, N—H⋯I hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001). |
format | Online Article Text |
id | pubmed-3393164 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931642012-07-17 catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] Cui, Sheng-Feng Wen, Qin-Mei Zhou, Cheng-He Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Cd(2)I(4)(C(6)H(14)N(2))(2)](n), there are two independent Cd(II) ions. One Cd(II) ion is coordinated in a slightly distorted octahedral coordination environment by four N atoms from two cyclohexane-1,2-diamine ligands and two iodido ligands. The other Cd(II) ion is coordinated by four iodido ligands in a slightly distorted tetrahedral coordination environment. Two of the iodido ligands act as bridging ligands connecting Cd(II) ions and forming a one-dimensional polymer along [010]. In the crystal, N—H⋯I hydrogen bonds connect the one-dimensional structure into a two-dimensional framework parallel to (001). International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393164/ /pubmed/22807732 http://dx.doi.org/10.1107/S1600536812024828 Text en © Cui et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Cui, Sheng-Feng Wen, Qin-Mei Zhou, Cheng-He catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2) N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] |
title |
catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2)
N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] |
title_full |
catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2)
N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] |
title_fullStr |
catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2)
N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] |
title_full_unstemmed |
catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2)
N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] |
title_short |
catena-Poly[[trans-bis(cyclohexane-1,2-diamine-κ(2)
N,N)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] |
title_sort | catena-poly[[trans-bis(cyclohexane-1,2-diamine-κ(2)
n,n)cadmium]-μ-iodido-(diiodidocadmium)-μ-iodido] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393164/ https://www.ncbi.nlm.nih.gov/pubmed/22807732 http://dx.doi.org/10.1107/S1600536812024828 |
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