Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate

The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was obtained by the solution reaction of MnCl(2) and 3-(2H-tetra­zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa­hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyri...

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Detalles Bibliográficos
Autores principales: Qi, Chen, He, Xiang, Shao, Min, Li, Ming-Xing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393165/
https://www.ncbi.nlm.nih.gov/pubmed/22807733
http://dx.doi.org/10.1107/S160053681202510X
Descripción
Sumario:The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was obtained by the solution reaction of MnCl(2) and 3-(2H-tetra­zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa­hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra­zolide ligands occupying trans positions and four water mol­ecules. In the crystal, the mononuclear complex mol­ecules and solvent water mol­ecules are connected into a three-dimensional framework by O—H⋯N and O—H⋯O hydrogen bonds.

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