Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate

The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was obtained by the solution reaction of MnCl(2) and 3-(2H-tetra­zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa­hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyri...

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Detalles Bibliográficos
Autores principales: Qi, Chen, He, Xiang, Shao, Min, Li, Ming-Xing
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393165/
https://www.ncbi.nlm.nih.gov/pubmed/22807733
http://dx.doi.org/10.1107/S160053681202510X
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author Qi, Chen
He, Xiang
Shao, Min
Li, Ming-Xing
author_facet Qi, Chen
He, Xiang
Shao, Min
Li, Ming-Xing
author_sort Qi, Chen
collection PubMed
description The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was obtained by the solution reaction of MnCl(2) and 3-(2H-tetra­zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa­hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra­zolide ligands occupying trans positions and four water mol­ecules. In the crystal, the mononuclear complex mol­ecules and solvent water mol­ecules are connected into a three-dimensional framework by O—H⋯N and O—H⋯O hydrogen bonds.
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spelling pubmed-33931652012-07-17 Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate Qi, Chen He, Xiang Shao, Min Li, Ming-Xing Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Mn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was obtained by the solution reaction of MnCl(2) and 3-(2H-tetra­zol-5-yl)pyridine. The Mn(II) atom, located on an inversion center, shows a slightly distorted octa­hedral geometry and is coordinated by two pyridine N atoms from two 5-(pyridin-3-yl)tetra­zolide ligands occupying trans positions and four water mol­ecules. In the crystal, the mononuclear complex mol­ecules and solvent water mol­ecules are connected into a three-dimensional framework by O—H⋯N and O—H⋯O hydrogen bonds. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393165/ /pubmed/22807733 http://dx.doi.org/10.1107/S160053681202510X Text en © Qi et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Qi, Chen
He, Xiang
Shao, Min
Li, Ming-Xing
Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate
title Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate
title_full Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate
title_fullStr Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate
title_full_unstemmed Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate
title_short Tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κN (5)]manganese(II) tetra­hydrate
title_sort tetra­aqua­bis­[5-(pyridin-3-yl)tetra­zolido-κn (5)]manganese(ii) tetra­hydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393165/
https://www.ncbi.nlm.nih.gov/pubmed/22807733
http://dx.doi.org/10.1107/S160053681202510X
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