Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]

In the title compound, [Na(C(11)H(11)ClN(3)O(3))(H(2)O)](n), there are two independent Na(I) ions, one of which lies on an inversion center and is coordinated in a slightly distorted octa­hedral environment. The other Na(I) ion lies on a twofold rotation axis and is cooordinated in a slightly distor...

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Autores principales: Kant, Rajni, Gupta, Vivek K., Kapoor, Kamini, Shripanavar, Chetan S., Banerjee, Kaushik, Deshmukh, Madhukar B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393166/
https://www.ncbi.nlm.nih.gov/pubmed/22807734
http://dx.doi.org/10.1107/S1600536812025007
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author Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
Deshmukh, Madhukar B.
author_facet Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
Deshmukh, Madhukar B.
author_sort Kant, Rajni
collection PubMed
description In the title compound, [Na(C(11)H(11)ClN(3)O(3))(H(2)O)](n), there are two independent Na(I) ions, one of which lies on an inversion center and is coordinated in a slightly distorted octa­hedral environment. The other Na(I) ion lies on a twofold rotation axis and is cooordinated in a slightly distorted trigonal–bipyramidal coordination environment. In the organic ligand, the imidazolidine ring adopts a half-chair conformation. The Na(I) ions bridge organic ligands and water mol­ecules, forming a two-dimensional structure parallel to (100). There are inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds within the two-dimensional structure.
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spelling pubmed-33931662012-07-17 Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium] Kant, Rajni Gupta, Vivek K. Kapoor, Kamini Shripanavar, Chetan S. Banerjee, Kaushik Deshmukh, Madhukar B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Na(C(11)H(11)ClN(3)O(3))(H(2)O)](n), there are two independent Na(I) ions, one of which lies on an inversion center and is coordinated in a slightly distorted octa­hedral environment. The other Na(I) ion lies on a twofold rotation axis and is cooordinated in a slightly distorted trigonal–bipyramidal coordination environment. In the organic ligand, the imidazolidine ring adopts a half-chair conformation. The Na(I) ions bridge organic ligands and water mol­ecules, forming a two-dimensional structure parallel to (100). There are inter­molecular O—H⋯O and weak C—H⋯O hydrogen bonds within the two-dimensional structure. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393166/ /pubmed/22807734 http://dx.doi.org/10.1107/S1600536812025007 Text en © Kant et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kant, Rajni
Gupta, Vivek K.
Kapoor, Kamini
Shripanavar, Chetan S.
Banerjee, Kaushik
Deshmukh, Madhukar B.
Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]
title Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]
title_full Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]
title_fullStr Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]
title_full_unstemmed Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]
title_short Poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]
title_sort poly[μ(2)-aqua-μ(4)-(2-{3-[(6-chloro­pyridin-3-yl)meth­yl]-2-oxoimidazolidin-1-yl}acetato)-sodium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393166/
https://www.ncbi.nlm.nih.gov/pubmed/22807734
http://dx.doi.org/10.1107/S1600536812025007
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