Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV)

The title compound, [Zr(3)(C(5)H(5))(6)Cl(2)O(2)], exists as discrete mol­ecules possessing a series of three Cp(2)Zr units (Cp is cyclo­penta­dien­yl) bridged by oxide ligands and end-capped by chloride ligands. The Cp planes in the central and terminal zirconocene units form dihedral angles of 53....

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Detalles Bibliográficos
Autores principales: Kraft, Bradley M., Brennessel, William W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393167/
https://www.ncbi.nlm.nih.gov/pubmed/22807735
http://dx.doi.org/10.1107/S1600536812024968
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author Kraft, Bradley M.
Brennessel, William W.
author_facet Kraft, Bradley M.
Brennessel, William W.
author_sort Kraft, Bradley M.
collection PubMed
description The title compound, [Zr(3)(C(5)H(5))(6)Cl(2)O(2)], exists as discrete mol­ecules possessing a series of three Cp(2)Zr units (Cp is cyclo­penta­dien­yl) bridged by oxide ligands and end-capped by chloride ligands. The Cp planes in the central and terminal zirconocene units form dihedral angles of 53.3 (2) and 53.5 (2)°, respectively. The two Zr—O—Zr bridge angles are nearly linear and form a planar Zr(3)O(2) core. The mol­ecule bears C2 symmetry with the central Zr atom lying on a crystallographic twofold axis.
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spelling pubmed-33931672012-07-17 Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV) Kraft, Bradley M. Brennessel, William W. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Zr(3)(C(5)H(5))(6)Cl(2)O(2)], exists as discrete mol­ecules possessing a series of three Cp(2)Zr units (Cp is cyclo­penta­dien­yl) bridged by oxide ligands and end-capped by chloride ligands. The Cp planes in the central and terminal zirconocene units form dihedral angles of 53.3 (2) and 53.5 (2)°, respectively. The two Zr—O—Zr bridge angles are nearly linear and form a planar Zr(3)O(2) core. The mol­ecule bears C2 symmetry with the central Zr atom lying on a crystallographic twofold axis. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393167/ /pubmed/22807735 http://dx.doi.org/10.1107/S1600536812024968 Text en © Kraft and Brennessel 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kraft, Bradley M.
Brennessel, William W.
Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV)
title Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV)
title_full Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV)
title_fullStr Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV)
title_full_unstemmed Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV)
title_short Dichlorido-1κCl,3κCl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) O:O;2:3κ(2) O:O-trizirconium(IV)
title_sort dichlorido-1κcl,3κcl-hexa­kis­[1,1,2,2,3,3(η(5))-cyclo­penta­dien­yl]di-μ(2)-oxido-1:2κ(2) o:o;2:3κ(2) o:o-trizirconium(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393167/
https://www.ncbi.nlm.nih.gov/pubmed/22807735
http://dx.doi.org/10.1107/S1600536812024968
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AT brennesselwilliamw dichlorido1kcl3kclhexakis112233ē5cyclopentadienyldim2oxido12k2oo23k2ootrizirconiumiv

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