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Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393168/ https://www.ncbi.nlm.nih.gov/pubmed/22807736 http://dx.doi.org/10.1107/S1600536812025081 |
Sumario: | In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methylbenzene and 2,4-dimethylbenzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intramolecular C—H⋯N hydrogen bond occurs. |
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