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Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)

In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl...

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Detalles Bibliográficos
Autores principales: Yusof, M. Sukeri M., Kadir, Maisara A., Yamin, Bohari M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393168/
https://www.ncbi.nlm.nih.gov/pubmed/22807736
http://dx.doi.org/10.1107/S1600536812025081
Descripción
Sumario:In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl­benzene and 2,4-dimethyl­benzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intra­molecular C—H⋯N hydrogen bond occurs.