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Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393168/ https://www.ncbi.nlm.nih.gov/pubmed/22807736 http://dx.doi.org/10.1107/S1600536812025081 |
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author | Yusof, M. Sukeri M. Kadir, Maisara A. Yamin, Bohari M. |
author_facet | Yusof, M. Sukeri M. Kadir, Maisara A. Yamin, Bohari M. |
author_sort | Yusof, M. Sukeri M. |
collection | PubMed |
description | In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methylbenzene and 2,4-dimethylbenzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intramolecular C—H⋯N hydrogen bond occurs. |
format | Online Article Text |
id | pubmed-3393168 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931682012-07-17 Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II) Yusof, M. Sukeri M. Kadir, Maisara A. Yamin, Bohari M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methylbenzene and 2,4-dimethylbenzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intramolecular C—H⋯N hydrogen bond occurs. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393168/ /pubmed/22807736 http://dx.doi.org/10.1107/S1600536812025081 Text en © Yusof et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Yusof, M. Sukeri M. Kadir, Maisara A. Yamin, Bohari M. Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II) |
title | Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2)
N,O}copper(II) |
title_full | Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2)
N,O}copper(II) |
title_fullStr | Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2)
N,O}copper(II) |
title_full_unstemmed | Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2)
N,O}copper(II) |
title_short | Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2)
N,O}copper(II) |
title_sort | bis{n-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2)
n,o}copper(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393168/ https://www.ncbi.nlm.nih.gov/pubmed/22807736 http://dx.doi.org/10.1107/S1600536812025081 |
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