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Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)

In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl...

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Autores principales: Yusof, M. Sukeri M., Kadir, Maisara A., Yamin, Bohari M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393168/
https://www.ncbi.nlm.nih.gov/pubmed/22807736
http://dx.doi.org/10.1107/S1600536812025081
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author Yusof, M. Sukeri M.
Kadir, Maisara A.
Yamin, Bohari M.
author_facet Yusof, M. Sukeri M.
Kadir, Maisara A.
Yamin, Bohari M.
author_sort Yusof, M. Sukeri M.
collection PubMed
description In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl­benzene and 2,4-dimethyl­benzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intra­molecular C—H⋯N hydrogen bond occurs.
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spelling pubmed-33931682012-07-17 Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II) Yusof, M. Sukeri M. Kadir, Maisara A. Yamin, Bohari M. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric mononuclear title complex, [Cu(C(18)H(20)N(2)O(2))(2)], the Cu(II) atom is four-coordinated in a trans-CuN(2)O(2) square-planar geometry with the N—Cu—O chelate angle being 89.97 (11)°. The dihedral angles made by the planes defined by the aromatic ring carbons of the 4-methyl­benzene and 2,4-dimethyl­benzene fragments with the plane defined by the chelate ring are 13.43 (15) and 82.69 (13)° respectively. The angle between the planes defined by the aromatic carbons of the two rings is 89.40 (16)°. A a weak intra­molecular C—H⋯N hydrogen bond occurs. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393168/ /pubmed/22807736 http://dx.doi.org/10.1107/S1600536812025081 Text en © Yusof et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yusof, M. Sukeri M.
Kadir, Maisara A.
Yamin, Bohari M.
Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
title Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
title_full Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
title_fullStr Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
title_full_unstemmed Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
title_short Bis{N-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) N,O}copper(II)
title_sort bis{n-[methoxy(4-methylbenzamido)methyl]-2,4-dimethylanilinido-κ(2) n,o}copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393168/
https://www.ncbi.nlm.nih.gov/pubmed/22807736
http://dx.doi.org/10.1107/S1600536812025081
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