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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxylate O atoms from two 5-bromosalicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-antiprismatic geometry. T...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393170/ https://www.ncbi.nlm.nih.gov/pubmed/22807738 http://dx.doi.org/10.1107/S1600536812025500 |
Sumario: | In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxylate O atoms from two 5-bromosalicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-antiprismatic geometry. The La(III) ions are linked by bridging carboxylate groups and chloride anions into a chain along [100]. An intramolecular O—H⋯O hydrogen bond is formed in the 5-bromosalicylate ligand. π–π interactions between the pyridine and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.794 (5) and 3.804 (4) Å]. |
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