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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxylate O atoms from two 5-bromosalicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-antiprismatic geometry. T...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393170/ https://www.ncbi.nlm.nih.gov/pubmed/22807738 http://dx.doi.org/10.1107/S1600536812025500 |
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author | Zhu, Wen-Qing Wang, Jin-Ping Yuan, Yu-Kun Li, Zhuo |
author_facet | Zhu, Wen-Qing Wang, Jin-Ping Yuan, Yu-Kun Li, Zhuo |
author_sort | Zhu, Wen-Qing |
collection | PubMed |
description | In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxylate O atoms from two 5-bromosalicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-antiprismatic geometry. The La(III) ions are linked by bridging carboxylate groups and chloride anions into a chain along [100]. An intramolecular O—H⋯O hydrogen bond is formed in the 5-bromosalicylate ligand. π–π interactions between the pyridine and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.794 (5) and 3.804 (4) Å]. |
format | Online Article Text |
id | pubmed-3393170 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931702012-07-17 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2) O (1):O (1′)-di-μ-chlorido] Zhu, Wen-Qing Wang, Jin-Ping Yuan, Yu-Kun Li, Zhuo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxylate O atoms from two 5-bromosalicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-antiprismatic geometry. The La(III) ions are linked by bridging carboxylate groups and chloride anions into a chain along [100]. An intramolecular O—H⋯O hydrogen bond is formed in the 5-bromosalicylate ligand. π–π interactions between the pyridine and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.794 (5) and 3.804 (4) Å]. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393170/ /pubmed/22807738 http://dx.doi.org/10.1107/S1600536812025500 Text en © Zhu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Zhu, Wen-Qing Wang, Jin-Ping Yuan, Yu-Kun Li, Zhuo catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2) O (1):O (1′)-di-μ-chlorido] |
title |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2)
O
(1):O
(1′)-di-μ-chlorido] |
title_full |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2)
O
(1):O
(1′)-di-μ-chlorido] |
title_fullStr |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2)
O
(1):O
(1′)-di-μ-chlorido] |
title_full_unstemmed |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2)
O
(1):O
(1′)-di-μ-chlorido] |
title_short |
catena-Poly[[(1,10-phenanthroline-κ(2)
N,N′)lanthanum(III)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2)
O
(1):O
(1′)-di-μ-chlorido] |
title_sort | catena-poly[[(1,10-phenanthroline-κ(2)
n,n′)lanthanum(iii)]-μ-(5-bromo-2-hydroxybenzoato)-κ(2)
o
(1):o
(1′)-di-μ-chlorido] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393170/ https://www.ncbi.nlm.nih.gov/pubmed/22807738 http://dx.doi.org/10.1107/S1600536812025500 |
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