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catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]

In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxyl­ate O atoms from two 5-bromo­salicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-anti­prismatic geometry. T...

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Detalles Bibliográficos
Autores principales: Zhu, Wen-Qing, Wang, Jin-Ping, Yuan, Yu-Kun, Li, Zhuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393170/
https://www.ncbi.nlm.nih.gov/pubmed/22807738
http://dx.doi.org/10.1107/S1600536812025500
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author Zhu, Wen-Qing
Wang, Jin-Ping
Yuan, Yu-Kun
Li, Zhuo
author_facet Zhu, Wen-Qing
Wang, Jin-Ping
Yuan, Yu-Kun
Li, Zhuo
author_sort Zhu, Wen-Qing
collection PubMed
description In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxyl­ate O atoms from two 5-bromo­salicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-anti­prismatic geometry. The La(III) ions are linked by bridging carboxyl­ate groups and chloride anions into a chain along [100]. An intra­molecular O—H⋯O hydrogen bond is formed in the 5-bromo­salicylate ligand. π–π inter­actions between the pyridine and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.794 (5) and 3.804 (4) Å].
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spelling pubmed-33931702012-07-17 catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido] Zhu, Wen-Qing Wang, Jin-Ping Yuan, Yu-Kun Li, Zhuo Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [La(C(7)H(4)BrO(3))Cl(2)(C(12)H(8)N(2))](n), the La(III) ion is eight-coordinated by two carboxyl­ate O atoms from two 5-bromo­salicylate ligands, two N atoms from a chelating 1,10-phenanthroline ligand and four bridging Cl atoms in a distorted square-anti­prismatic geometry. The La(III) ions are linked by bridging carboxyl­ate groups and chloride anions into a chain along [100]. An intra­molecular O—H⋯O hydrogen bond is formed in the 5-bromo­salicylate ligand. π–π inter­actions between the pyridine and benzene rings and between the benzene rings are observed [centroid–centroid distances = 3.794 (5) and 3.804 (4) Å]. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393170/ /pubmed/22807738 http://dx.doi.org/10.1107/S1600536812025500 Text en © Zhu et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Zhu, Wen-Qing
Wang, Jin-Ping
Yuan, Yu-Kun
Li, Zhuo
catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
title catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
title_full catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
title_fullStr catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
title_full_unstemmed catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
title_short catena-Poly[[(1,10-phenanthroline-κ(2) N,N′)lanthanum(III)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) O (1):O (1′)-di-μ-chlorido]
title_sort catena-poly[[(1,10-phenanthroline-κ(2) n,n′)lanthanum(iii)]-μ-(5-bromo-2-hy­droxy­benzoato)-κ(2) o (1):o (1′)-di-μ-chlorido]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393170/
https://www.ncbi.nlm.nih.gov/pubmed/22807738
http://dx.doi.org/10.1107/S1600536812025500
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