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(Acetato-κO)(acetato-κ(2) O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc(II)
The Zn(II) atom in the title compound, [Zn(C(2)H(3)O(2))(2)(C(14)H(13)N(3))], is coordinated by an N(2)O(3) donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands....
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2012
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393171/ https://www.ncbi.nlm.nih.gov/pubmed/22807739 http://dx.doi.org/10.1107/S1600536812025664 |
| _version_ | 1782237687445454848 |
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| author | Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Najib, Muhd. Hidayat bin |
| collection | PubMed |
| description | The Zn(II) atom in the title compound, [Zn(C(2)H(3)O(2))(2)(C(14)H(13)N(3))], is coordinated by an N(2)O(3) donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O—Zn—O = 59.65 (5) and N—Zn—N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋯O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C—H⋯O interactions |
| format | Online Article Text |
| id | pubmed-3393171 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2012 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-33931712012-07-17 (Acetato-κO)(acetato-κ(2) O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc(II) Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Zn(II) atom in the title compound, [Zn(C(2)H(3)O(2))(2)(C(14)H(13)N(3))], is coordinated by an N(2)O(3) donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O—Zn—O = 59.65 (5) and N—Zn—N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn⋯O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C—H⋯O interactions International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393171/ /pubmed/22807739 http://dx.doi.org/10.1107/S1600536812025664 Text en © Najib et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Najib, Muhd. Hidayat bin Tan, Ai Ling Young, David J. Ng, Seik Weng Tiekink, Edward R. T. (Acetato-κO)(acetato-κ(2) O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN (2))quinoline-κN]zinc(II) |
| title | (Acetato-κO)(acetato-κ(2)
O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc(II) |
| title_full | (Acetato-κO)(acetato-κ(2)
O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc(II) |
| title_fullStr | (Acetato-κO)(acetato-κ(2)
O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc(II) |
| title_full_unstemmed | (Acetato-κO)(acetato-κ(2)
O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc(II) |
| title_short | (Acetato-κO)(acetato-κ(2)
O,O′)[2-(3,5-dimethyl-1H-pyrazol-1-yl-κN
(2))quinoline-κN]zinc(II) |
| title_sort | (acetato-κo)(acetato-κ(2)
o,o′)[2-(3,5-dimethyl-1h-pyrazol-1-yl-κn
(2))quinoline-κn]zinc(ii) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393171/ https://www.ncbi.nlm.nih.gov/pubmed/22807739 http://dx.doi.org/10.1107/S1600536812025664 |
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