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Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]

In the title coordination polymer, [Cd(2)(C(4)H(4)O(4))(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) ion is seven-coordinated within a distorted penta­gonal–bipyramidal O(5)N(2) environment. The succinate anions, located on an inversion centre, adopt a bis-monodentate bridging mode, leading...

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Detalles Bibliográficos
Autores principales: Li, Hong-Jin, Gao, Zhu-Qing, Gu, Jin-Zhong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2012
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393172/
https://www.ncbi.nlm.nih.gov/pubmed/22807740
http://dx.doi.org/10.1107/S1600536812025287
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author Li, Hong-Jin
Gao, Zhu-Qing
Gu, Jin-Zhong
author_facet Li, Hong-Jin
Gao, Zhu-Qing
Gu, Jin-Zhong
author_sort Li, Hong-Jin
collection PubMed
description In the title coordination polymer, [Cd(2)(C(4)H(4)O(4))(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) ion is seven-coordinated within a distorted penta­gonal–bipyramidal O(5)N(2) environment. The succinate anions, located on an inversion centre, adopt a bis-monodentate bridging mode, leading to the formation of rods along [100]. The rods are connected by O—H⋯O hydrogen bonds between the coordinating water mol­ecules and nitrate O atoms of adjacent rods; the same type of hydrogen bonds are also observed between water and carboxyl­ate O atoms within the rods. π–π stacking inter­actions with a minimum plane-to-plane separation of 3.462 (2) Å occur between phenanthroline ligands.
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spelling pubmed-33931722012-07-17 Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium] Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(2)(C(4)H(4)O(4))(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) ion is seven-coordinated within a distorted penta­gonal–bipyramidal O(5)N(2) environment. The succinate anions, located on an inversion centre, adopt a bis-monodentate bridging mode, leading to the formation of rods along [100]. The rods are connected by O—H⋯O hydrogen bonds between the coordinating water mol­ecules and nitrate O atoms of adjacent rods; the same type of hydrogen bonds are also observed between water and carboxyl­ate O atoms within the rods. π–π stacking inter­actions with a minimum plane-to-plane separation of 3.462 (2) Å occur between phenanthroline ligands. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393172/ /pubmed/22807740 http://dx.doi.org/10.1107/S1600536812025287 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Li, Hong-Jin
Gao, Zhu-Qing
Gu, Jin-Zhong
Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]
title Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]
title_full Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]
title_fullStr Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]
title_full_unstemmed Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]
title_short Poly[diaqua­bis­(nitrato-κ(2) O,O′)bis­(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]
title_sort poly[diaqua­bis­(nitrato-κ(2) o,o′)bis­(1,10-phenanthroline-κ(2) n,n′)-μ(3)-succinato-dicadmium]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393172/
https://www.ncbi.nlm.nih.gov/pubmed/22807740
http://dx.doi.org/10.1107/S1600536812025287
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