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Poly[diaquabis(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium]
In the title coordination polymer, [Cd(2)(C(4)H(4)O(4))(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) ion is seven-coordinated within a distorted pentagonal–bipyramidal O(5)N(2) environment. The succinate anions, located on an inversion centre, adopt a bis-monodentate bridging mode, leading...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2012
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393172/ https://www.ncbi.nlm.nih.gov/pubmed/22807740 http://dx.doi.org/10.1107/S1600536812025287 |
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author | Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
author_facet | Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong |
author_sort | Li, Hong-Jin |
collection | PubMed |
description | In the title coordination polymer, [Cd(2)(C(4)H(4)O(4))(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) ion is seven-coordinated within a distorted pentagonal–bipyramidal O(5)N(2) environment. The succinate anions, located on an inversion centre, adopt a bis-monodentate bridging mode, leading to the formation of rods along [100]. The rods are connected by O—H⋯O hydrogen bonds between the coordinating water molecules and nitrate O atoms of adjacent rods; the same type of hydrogen bonds are also observed between water and carboxylate O atoms within the rods. π–π stacking interactions with a minimum plane-to-plane separation of 3.462 (2) Å occur between phenanthroline ligands. |
format | Online Article Text |
id | pubmed-3393172 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2012 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-33931722012-07-17 Poly[diaquabis(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium] Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Cd(2)(C(4)H(4)O(4))(NO(3))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)](n), the Cd(II) ion is seven-coordinated within a distorted pentagonal–bipyramidal O(5)N(2) environment. The succinate anions, located on an inversion centre, adopt a bis-monodentate bridging mode, leading to the formation of rods along [100]. The rods are connected by O—H⋯O hydrogen bonds between the coordinating water molecules and nitrate O atoms of adjacent rods; the same type of hydrogen bonds are also observed between water and carboxylate O atoms within the rods. π–π stacking interactions with a minimum plane-to-plane separation of 3.462 (2) Å occur between phenanthroline ligands. International Union of Crystallography 2012-06-13 /pmc/articles/PMC3393172/ /pubmed/22807740 http://dx.doi.org/10.1107/S1600536812025287 Text en © Li et al. 2012 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Li, Hong-Jin Gao, Zhu-Qing Gu, Jin-Zhong Poly[diaquabis(nitrato-κ(2) O,O′)bis(1,10-phenanthroline-κ(2) N,N′)-μ(3)-succinato-dicadmium] |
title | Poly[diaquabis(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)-μ(3)-succinato-dicadmium] |
title_full | Poly[diaquabis(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)-μ(3)-succinato-dicadmium] |
title_fullStr | Poly[diaquabis(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)-μ(3)-succinato-dicadmium] |
title_full_unstemmed | Poly[diaquabis(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)-μ(3)-succinato-dicadmium] |
title_short | Poly[diaquabis(nitrato-κ(2)
O,O′)bis(1,10-phenanthroline-κ(2)
N,N′)-μ(3)-succinato-dicadmium] |
title_sort | poly[diaquabis(nitrato-κ(2)
o,o′)bis(1,10-phenanthroline-κ(2)
n,n′)-μ(3)-succinato-dicadmium] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3393172/ https://www.ncbi.nlm.nih.gov/pubmed/22807740 http://dx.doi.org/10.1107/S1600536812025287 |
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